首页|冀东代表性铁尾矿库表层重金属含量特征及生态风险评价

冀东代表性铁尾矿库表层重金属含量特征及生态风险评价

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冀东是国内沉积变质型铁矿(BIF)的重要分布区,但其尾矿重金属元素含量特征及迁移规律研究较为薄弱.以国内代表性BIF型铁矿——河北钢铁集团司家营铁矿研山、二号尾矿库样品为研究对象,依据重金属元素Pb、Cr、Cd、Cu、Zn、As、Hg和Ni的含量及变化特征,探讨尾矿中重金属元素含量水平和垂直空间的含量变化.并利用单因子污染指数法、内梅罗综合污染指数法和潜在生态风险指数法对尾矿库的重金属污染特征及生态风险进行了评价.结果表明:① 司家营研山尾矿库部分点位中的Cr、Cu、Ni和Cd含量超过背景值,司家营二号尾矿库部分点位中Cu、Cr和Pb含量超过背景值;且两尾矿库重金属形态以Fe-Mn氧化物结合态和残渣态为主,重金属有效态占比较高.② 在垂向上,两尾矿库重金属呈现由表层向次表层迁移趋势;在水平上,两尾矿库不同区域内,重金属总量均呈现向库内迁移趋势.③ 单因子污染指数和内梅罗污染指数表明,司家营研山尾矿库中重金属污染程度排序为Cd>Ni>Cu>Cr,处于轻污染;司家营二号尾矿库中重金属污染程度排序为Cu>Cr>Ni>Pb,Cu为中污染、Cr为轻污染、Ni和Pb为警戒级.潜在生态风险指数表明,两尾矿库的潜在生态风险指数RI均为轻度生态危害等级.总体上,该地区铁尾矿存在一定的重金属污染风险,应加强动态监测和生态修复治理,防止重金属污染进一步发生.
Characterization of Surface Heavy Metal Content and Ecological Risk Evaluation of Representative Iron Tailing Ponds in Eastern Hebei Province
Eastern Hebei Province is an important distribution area of sedimentary metamorphic iron ore(BIF)in Chi-na,but the study on the content characteristics and migration pattern of heavy metals in its tailings is relatively weak.In this paper,the horizontal and vertical spatial content changes of heavy metals in tailings were investigated based on the content and variation characteristics of heavy metal elements Pb,Cr,Cd,Cu,Zn,As,Hg and Ni,using samples from the Yanshan and No.2 tailings ponds of Sijiaying Iron Mine of Hebei Iron and Steel Group,a representative BIF-type iron ore mine in China as the study object.Based on this,the heavy metal pollution characteristics and ecological risks of the tailings ponds were evaluated by using the single factor pollution index method,the Nemero integrated pollution index method and the potential ecological risk index method.The results showe that:① the content of elemental Cr,Cu,Ni and Cd in some points of Sijiaying Yanshan tail-ings pond exceeded the background value;the content of elemental Cu,Cr and Pb in some points of Sijiaying No.2 tailings pond exceeded the background value;and the heavy metal forms in the two tailings ponds were mainly Fe-Mn oxide-binding state and residue state,and the effective state of heavy metals accounted for a higher percentage.② In the vertical direction,the heavy metals in the two tailing ponds showed a trend of migration from the surface layer to the subsurface layer;in the hori-zontal direction,the total heavy metals in different areas of the two tailing ponds showed a trend of migration to the pond.③ The single-factor and Nemero pollution indices show that the pollution level of heavy metals in Sijiaying Yanshan tailings pond is ranked as Cd>Ni>Cu>Cr,which is in light pollution;the pollution level of heavy metals in Sijiaying No.2 tailings pond is ranked as Cu>Cr>Ni>Pb,with Cu as medium pollution,Cr as light pollution,Ni and Pb as alert level.The potential ecologi-cal risk index indicates that the potential ecological risk index RI of both tailings ponds is a mild ecological hazard level.Over-all,there is a certain risk of heavy metal pollution in the iron tailings in the area,and dynamic monitoring and ecological resto-ration treatment should be strengthened to stop further heavy metal pollution.

iron tailings pondheavy metalscontent characteristicsecological risk assessment

张振国、王月、陈军典、高倩、邢杰、骆念岗、田释梦、代佳浩

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辽宁工程技术大学矿业学院,辽宁 阜新 123000

辽宁省物测勘查院有限责任公司,辽宁 沈阳 110031

辽宁省地质矿产调查院有限责任公司,辽宁 沈阳 110031

铁尾矿库 重金属 含量特征 生态风险评价

国家自然科学基金项目国家自然科学基金项目河北省自然科学基金项目河北省自然科学基金项目河北省教育厅自然科学基金重点项目

4117201541972004D2017209236E2019209339ZD2016077

2024

金属矿山
中钢集团马鞍山矿山研究院 中国金属学会

金属矿山

CSTPCD北大核心
影响因子:0.935
ISSN:1001-1250
年,卷(期):2024.(7)