首页|焙烧预处理强化钼铜分离试验及机理研究

焙烧预处理强化钼铜分离试验及机理研究

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为解决钼铜混合精矿的铜钼浮选分离难题,以某选厂钼铜混合精矿为研究对象,探究了焙烧预处理对钼、铜浮选分离效果的影响.结果表明:焙烧预处理能有效改善钼铜混合精矿的浮选分离效果,确定的适宜焙烧预处理条件为焙烧温度250℃,焙烧时间30 min.预处理产品采用1粗2精1扫浮选流程处理,可获得钼精矿钼品位为44.30%、钼回收率为36.58%,铜精矿铜品位为14.23%、铜回收率为69.62%.焙烧产品的XRD和SEM-EDS分析结果表明,样品在焙烧过程中,主要矿物辉钼矿和黄铜矿均可发生氧化反应;当焙烧温度为250 ℃时,黄铜矿的表面氧化程度远高于辉钼矿,从而增大了两者可浮性差异,为有效分离铜、钼矿物分离创造了条件.
Experimental and Mechanism Study on Strengthening Separation of Molybdenum and Copper by Roasting Pretreatment
In order to solve the problem of flotation separation of molybdenum-copper mixed concentrate,the influence of roasting pretreatment on flotation separation of molybdenum-copper mixed concentrate in a concentrator was studied.The results showed that the calcination pretreatment can effectively improve the flotation separation effect of molybdenum copper mixed concentrate.The optimum calcination pretreatment conditions are calcination temperature of 250 ℃ and calcination time of 30 min.The pretreatment products were treated with one roughing,two cleaning and one scavenging flotation process,and the mo-lybdenum grade of molydenum concentrate was 44.30%and the molybdenum recovery of molydenum concentrate was 36.58%,and the copper concentrate grade was 14.23%and the copper recovery was 69.62%.The results of XRD and SEM-EDS analysis of the calcined products showed that molybdenum and chalcopyrite can be oxidized during the calcination process.When the roasting temperature is 250 ℃,the surface oxidation degree of chalcopyrite is much higher than that of mo-lybdenite,which increases the difference of floatability between the two,creating conditions for the effective separation of copper and molybdenum minerals.

Mo-Cu mixed concentrateroastingpretreatmentflotation

马敏洁、韩跃新、李慧

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东北大学资源与土木工程学院,辽宁沈阳 110819

沈阳建筑大学材料科学与工程学院,辽宁沈阳 110623

铜钼混合精矿 焙烧 预处理 浮选

国家自然科学基金项目国家自然科学基金项目

5227425651904222

2024

金属矿山
中钢集团马鞍山矿山研究院 中国金属学会

金属矿山

CSTPCD北大核心
影响因子:0.935
ISSN:1001-1250
年,卷(期):2024.(9)