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贵州某赤泥工艺矿物学特性研究

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为深入探究贵州某赤泥中铝铁钛矿物组成、嵌布特征及元素赋存形式,明确适宜的回收方法,对其开展了工艺矿物学研究.分别采用化学多元素分析、激光粒度仪分析和SEM-EDS-BPMA矿物自动定量分析系统对赤泥的化学组成、粒度特性、元素分布和矿物嵌布特征进行了详细分析.研究结果表明,赤泥样品中富含铁、铝和钛等可具回收价值的金属成分;赤泥粒度极细,-25 μm的产率高达77.60%.矿物组成复杂,主要矿物包括赤铁矿、铝硅酸铁、铁铝硅酸钙和钙铁氧化物.赤铁矿富连生体较多,嵌布粒度较粗;然而,硬水铝石和金红石等矿物含量较低,嵌布粒度细小,分布稀散,分离提取难度较大.本研究进一步明确了铝、铁、钛在赤泥中的赋存形式,为拜耳法赤泥制定高效利用方案提供了重要矿物学依据.
Study on Process Mineralogical Characteristics of a Mud in Guizhou
A process mineralogy study was carried out to investigate the mineral composition,embedding characteristics and elemental distribution of aluminum,iron and titanium in a red mud in Guizhou Province,and to identify suitable recovery methods.The chemical composition,particle size characteristics,elemental distribution and mineral embedding characteristics of the red mud were analyzed in detail by chemical multi-element analysis,laser particle sizer analysis and SEM-EDS-BPMA automatic quantitative mineral analysis system.The results showed that the red mud samples are rich in iron,aluminum and ti-tanium,which can be recycled;Its particle size is very fine,and the yield of-25 p.m is as high as 77.60%.The mineral com-position is complex,and the main minerals include hematite,iron aluminum silicate,calcium iron aluminum silicate,and calci-um iron oxide.Hematite-rich concretions are more abundant and have a coarse embedded grain size;However,minerals such as stibnite and rutile are low in content,have a fine embedded grain size,are sparsely distributed,and are difficult to separate and extract.The present study further clarifies the forms of aluminum,iron and titanium elements in red mud,which provides an im-portant mineralogical theoretical basis for the development of an efficient utilization scheme for Bayer process red mud.

Bayer red mudprocess mineralogydissociation degreestate of element's assignment

刘文宝、张覃、王永伦、沈岩柏、刘文刚

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贵州科学院,贵州贵阳 550001

东北大学资源与土木工程学院,辽宁沈阳 110819

拜耳法赤泥 工艺矿物学 解离度 元素赋存状态

贵州省省级科技计划项目中国博士后科学基金项目

黔科合支撑[2023]一般1422022M720927

2024

金属矿山
中钢集团马鞍山矿山研究院 中国金属学会

金属矿山

CSTPCD北大核心
影响因子:0.935
ISSN:1001-1250
年,卷(期):2024.(9)