首页|2-乙基己基磷酸酯对萤石和方解石浮选行为的影响及机理

2-乙基己基磷酸酯对萤石和方解石浮选行为的影响及机理

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萤石常与方解石等脉石矿物伴生,二者表面都有Ca活性位点,使得脂肪酸类捕收剂难以选择性吸附于萤石表面.前期试验发现磷酸酯类药剂对萤石具有选择性捕收能力,且捕收能力较强,有利于分离萤石和方解石.通过浮选试验研究了 2-乙基己基磷酸酯(2ZHP)对萤石和方解石浮选行为的影响,并采用Zeta电位、红外光谱、X射线光电子能谱等分析手段,探究药剂的作用机理.结果表明:在pH值为4~7 时,添加0.75×10-5 mol/L的2ZHP,萤石有较好的可浮性,与方解石的可浮性差异较大,有利于实现萤石与方解石的浮选分离;2ZHP 能在萤石与方解石表面发生不同程度的化学吸附,萤石表面钙活性位点多,导致萤石对药剂的吸附量比方解石大是萤石的浮选效果优于方解石的主要原因.
Effect of 2-ethylhexyl Phosphate on Flotation Behavior of Fluorite and Calcite and Mechanism Study
Fluorite is often associated with gangue minerals such as calcite,and both surfaces have Ca active sites,mak-ing it difficult for fatty acid collectors to selectively adsorb on the surface of fluorite.Previous experiments have found that phos-phate esters have selective collecting ability for fluorite,and the collecting ability is strong,which is beneficial to the separation of fluorite and calcite.The effect of 2-ethylhexyl phosphate(2ZHP)on the flotation behavior of fluorite and calcite was studied by flotation test,and the mechanism of the reagent was explored by Zeta potential,infrared spectroscopy,X-ray photoelectron spectroscopy and other analytical methods.The results show that fluorite has better floatability when 0.75×10-5 mol/L 2ZHP is added at pH 4~7.Fluorite has good floatability,which is quite different from that of calcite,which is conducive to the flotation separation of fluorite and calcite.2ZHP can have different degrees of chemical adsorption on the surface of fluorite and calcite.There are many calcium active sites on the surface of fluorite,which leads to the larger adsorption capacity of fluorite to the a-gent than that of calcite,which is the main reason for the better flotation effect of fluorite than that of calcite.

2-ethylhexyl phosphatefluoritecalciteflotation

汤家焰、赵芳、何嘉宁、王介良、曹钊、魏博、张臻悦、池汝安

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内蒙古科技大学矿业与煤炭学院,内蒙古 包头 014010

内蒙古自治区矿业工程重点实验室,内蒙古 包头 014010

内蒙古自治区煤炭安全开采与利用工程技术研究中心,内蒙古 包头 014010

内蒙古煤炭绿色开采与绿色利用协同创新中心,内蒙古 包头 014010

建筑材料工业技术情报研究所,北京 100020

武汉工程大学资源与安全工程学院,湖北 武汉 430205

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2-乙基己基磷酸酯 萤石 方解石 浮选

2024

金属矿山
中钢集团马鞍山矿山研究院 中国金属学会

金属矿山

CSTPCD北大核心
影响因子:0.935
ISSN:1001-1250
年,卷(期):2024.(12)