首页|臭氧活性炭工艺处理多种新污染物复合污染研究

臭氧活性炭工艺处理多种新污染物复合污染研究

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以南方某流域水体可检出的SD、SMZ、HCB、马拉硫磷和BPA等新污染物为研究对象,进行复合新污染物共存的原水加标处理试验,研究预处理-常规处理-臭氧活性炭工艺处理效果.结果表明,SD、SMZ、BPA与CODMn 均具有较好的相关性;生物预处理工艺对 SD、SMZ、HCB、马拉硫磷和BPA去除率分别为 23.97%、21.20%、6.08%、16.26%和 23.76%,生物预处理最优停留时间是 120 min,最优气水比是 1∶2;常规处理工艺对 SD、SMZ、HCB、马拉硫磷和 BPA 的去除率分别为18.02%、20.08%、23.02%、8.26%和 16.53%,常规处理中SMZ和马拉硫磷的混凝剂最佳投加量为15 mg/L,其余 3 种新污染物的混凝剂最佳投加量为 20 mg/L;深度处理工艺对 SD、SMZ、HCB、马拉硫磷和BPA的去除率分别为 49.13%、53.80%、60.20%、77.07%和 71.50%,深度处理最佳臭氧投加量是 3 mg/L,最佳臭氧接触时间为 24 min,最优炭床停留时间是 25 min.试验工艺对复合新污染物具有良好的去除作用,对 SD、SMZ、HCB、马拉硫磷和 BPA 的总去除率达到了 69.86%、73.10%、73.65%、83.74%和 82.72%,试验条件下出水的 HCB、马拉硫磷和BPA满足《生活饮用水卫生标准》(GB 5749-2022),出水的磺胺嘧啶和磺胺二甲嘧啶满足欧美发达国家的水质标准.
Study on the treatment of multiple new pollutant compound pollution by ozone activated carbon process
Taking emerging pollutants such as SD,SMZ,HCB,malathion,and BPA that can be detected in a water basin in the south as the research object,a composite new pollutant co exist-ing raw water spiking treatment experiment was conducted to study the treatment effect of pre-treatment+conventional treatment+ozone activated carbon process.The results indicate that SD,SMZ,BPA and CODMn all have good correlation.The removal rates of SD,SMZ,HCB,malathi-on,and BPA by the biological pretreatment process are 23.97%,21.20%,6.08%,16.26%,and 23.76%,respectively.The optimal residence time for biological pretreatment is 120 minutes,and the optimal gas water ratio is 1∶2.The removal rates of SD,SMZ,HCB,malathion,and BPA by conventional treatment processes are 18.02%,20.08%,23.02%,8.26%,and 16.53%,respec-tively.The optimal dosage of coagulants for SMZ and malathion in conventional treatment is 15 mg/L,while the optimal dosage of coagulants for the other three new pollutants is 20 mg/L;The removal rates of SD,SMZ,HCB,malathion,and BPA by the deep treatment process are 49.13%,53.80%,60.20%,77.07%,and 71.50%,respectively.The optimal ozone dosage for deep treatment is 3 mg/L,the optimal ozone contact time is 24 minutes,and the optimal carbon bed retention time is 25 minutes.The experimental process has a good removal effect on composite new pollutants,with a total removal rate of 69.86%,73.10%,73.65%,83.74%,and 82.72%for SD,SMZ,HCB,malathion,and BPA.Under the experimental conditions,the HCB,malathi-on,and BPA in the effluent are better than the indicators specified in the Sanitary Standards for Drinking Water(GB 5749-2022),and the sulfamethoxazole and sulfamethoxazole in the effluent are better than the water quality indicators required by developed countries in Europe and America.

Water supply treatmentEmerging pollutantpretreatmentConventional processOzone-activated carbonOptimization

钟志聪、赫俊国、吴学伟、袁永钦、尹文选、谭俊杰、张道义、吴雨晴

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广州大学土木工程学院,广州 510000

广州市水务投资集团有限公司,广州 510655

广州市自来水有限公司,广州 510600

广州市市政工程设计研究总院有限公司,广州 510095

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给水处理 新污染物 预处理 常规工艺 臭氧活性炭

2024

给水排水
亚太建设科技信息研究院,中国建筑设计研究院,中国土木工程学会

给水排水

CSTPCD北大核心
影响因子:0.8
ISSN:1002-8471
年,卷(期):2024.50(3)