首页|用于饮用水处理的商品纳滤膜理化特性与过滤性能研究

用于饮用水处理的商品纳滤膜理化特性与过滤性能研究

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针对市政给水领域纳滤工程科学选膜的需求,对18种市售商品纳滤膜进行了理化性质表征与过滤性能评测.结果表明,纳滤膜的纯水渗透系数大多为10~20 LMH/bar;全芳香族与半芳香族聚酰胺膜在形貌结构、官能团组成、表面亲水性与孔径分布方面差异显著.处理天然水时,所有纳滤膜对有机物截留率均高于70%;全芳香族聚酰胺膜大多具有高脱盐率(>90%);半芳香族聚酰胺膜的脱盐率基本在20%~60%,对硬度离子截留率的差异较大.对于苦咸地下水处理等高脱盐需求的应用场景,应选用全芳香族聚酰胺膜;针对去除有机物、保留无机盐的净水需求,建议选用截留相对分子质量为330 Da左右的半芳香族聚酰胺膜.
Research on the physicochemical properties and filtration performance of commercial nanofiltration membranes for drinking water treatment
Aiming at the demand for scientific membrane selection for nanofiltration projects in the field of municipal water supply,18 kinds of commercially available nanofiltration membranes were characterized for their physicochemical properties and evaluated for filtration performance.The results show that the pure water permeance of nanofiltration membranes was mostly 10~20 LMH/bar.There were significant differences between fully aromatic and semi-aromatic polyamide membranes in terms of morphological structure,functional group composition,surface hydrophilicity and pore size distribution.When treating natural water,all nanofiltration mem-branes had a rejection rate of organic matters higher than 70%.Most of the fully aromatic polyam-ide membranes had a high salt rejection(>90%),while that of the semi-aromatic polyamide mem-branes was basically 20%~60%with a particularly large distinction in hardness ion rejections.For desalination applications such as brackish groundwater treatment,fully aromatic polyamide mem-branes should be selected.To meet the water purification requirements of removing organic mat-ters and preserving inorganic salts,it is recommended to use semi-aromatic polyamide membranes with a molecular weight cutoff of about 330 Da.

Nanofiltration membraneWater treatmentPhysicochemical propertiesFiltration performance

翟春霖、段冬、张欣然、刘彦伶、夏圣骥

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同济大学环境科学与工程学院,上海 200092

上海市政工程设计研究总院(集团)有限公司,上海 200092

纳滤膜 给水处理 理化性质 过滤性能

上海市"科技创新行动计划"自然科学基金面上项目

23ZR1466400

2024

给水排水
亚太建设科技信息研究院,中国建筑设计研究院,中国土木工程学会

给水排水

CSTPCD北大核心
影响因子:0.8
ISSN:1002-8471
年,卷(期):2024.50(6)