给水排水2024,Vol.50Issue(6) :85-91.DOI:10.13789/j.cnki.wwe1964.2023.11.06.0003

基于光谱法分析纳滤截留典型消毒副产物相关性研究

Correlation of typical disinfection by-products retained by nanofiltration in pilot-scale study based on spectral analysis

王一帆 邱晓鹏 张静 杨非凡 李晓良 冯民权 顾军农 郑兴
给水排水2024,Vol.50Issue(6) :85-91.DOI:10.13789/j.cnki.wwe1964.2023.11.06.0003

基于光谱法分析纳滤截留典型消毒副产物相关性研究

Correlation of typical disinfection by-products retained by nanofiltration in pilot-scale study based on spectral analysis

王一帆 1邱晓鹏 1张静 2杨非凡 3李晓良 1冯民权 1顾军农 2郑兴4
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作者信息

  • 1. 西安理工大学西北旱区生态水利国家重点实验室,西安 710048
  • 2. 北京市自来水集团有限责任公司技术研究院北京市供水水质工程技术研究中心,北京 100101
  • 3. 不列颠哥伦比亚大学土木工程系,温哥华 V6T1Z4
  • 4. 浙江科技大学环境与资源学院,杭州 310018
  • 折叠

摘要

为提高北方某给水厂水资源利用率,采用纳滤工艺对超滤产水进行深度处理,对比研究了5种纳滤膜(T膜、H膜、F膜、N270膜与N90膜)对出水水质的提升效果,探讨了三维荧光及紫外(差分)光谱法对典型消毒副产物(DBPs)的指示作用.结果表明,N90膜对超滤产水中的三氯甲烷(TCM)和一溴二氯甲烷(BDCM)的截留率最为理想,分别为76.29%和100%,N270膜次之,而T膜截留效果最差.采用三维荧光平行因子分析法(EEM-PARAFAC)分析纳滤进出水得到C1类富里酸、C2类腐殖酸以及C3微生物代谢产物,同时利用差分光谱进行高斯拟合得到A1~A4 4个特征峰.基于EEM-PARAFAC分析得到的C2组分与TCM相关性最高为0.83,通过差分光谱分析得到的A3与BDCM相关性最高0.68.

Abstract

To enhance water resource utilization at a water treatment plant in North,Nanofil-tration(NF)technology was employed to treat Ultrafiltration(UF)effluent derived from the backwash water of the plant's filtration process.A comparative investigation was conducted to as-sess the impact of five distinct NF membranes(T membrane,H membrane,F membrane,N270 membrane,and N90 membrane)on the quality improvement of the treated water.Additionally,this study explored the applicability of the EEM and UV spectroscopy(Different absorbance)in in-dicating the presence of typical DBPs.The results revealed that the N90 membrane exhibited the i-deal retention rates for TCM and BDCM in the UF effluent,achieving 76.29%and 100%respec-tively.The N270 membrane followed closely,while the T membrane demonstrated a comparative-ly lower retention effect.EEM-PARAFAC analysis of the UF effluent identified major components such as C1 fulvic acid,C2 humic acid,and C3 microbial metabolites.Furthermore,Gaussian fit-ting of different absorbance spectroscopy(DAS)in influent and effluent water revealed four charac-teristic peaks denoted as A1 to A4.Correlation analysis between spectral parameters and DBPs indi-cated that,for TCM,the component C2 derived from PARAFAC analysis exhibited the highest correlation coefficient at 0.83.In the case of BDCM,the highest correlation at 0.68 was observed with A3 obtained from DAS.This study aimed to identify the most suitable NF membrane for im-proving the water quality of the plant and provides valuable insights for predicting subsequent wa-ter quality regarding the impact of DBPs on regeneration and reuse.

关键词

纳滤/三维荧光光谱/差分光谱/消毒副产物

Key words

Nanofiltration/Three-dimensional fluorescence spectroscopy/Different absorbance spectroscopy/Disinfection byproducts

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基金项目

国家自然科学基金(52100104)

国家自然科学基金(52170053)

出版年

2024
给水排水
亚太建设科技信息研究院,中国建筑设计研究院,中国土木工程学会

给水排水

CSTPCDCSCD北大核心
影响因子:0.8
ISSN:1002-8471
参考文献量17
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