首页|长江下游典型城市水源水中农药分布及水厂工艺去除效果研究

长江下游典型城市水源水中农药分布及水厂工艺去除效果研究

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建立了一种能同时分析水中190种农药的气相色谱-质谱联用(GC-MS/MS)方法,并选取长江下游5个城市13个饮用水厂,调查了农药在进水中的分布及水厂工艺的去除效果.结果表明,仪器检出限为0.01~7.2 ng/L,回收率为50.8%~130.1%.水源中共检出53种农药,总浓度为198.8~759.2 ng/L.其中,多效唑、γ-六六六、异丙甲草胺、环嗪酮和戊唑醇在水源水中检出率为100%,平均浓度为11.5~63.8 ng/L;多效唑、马拉硫磷、三硫磷、地茂散和γ-六六六为平均浓度最高的5种农药(30.4~101.2 ng/L).γ-六六六作为一种被禁用的有机氯农药被广泛检出,表明有必要加强对农药生产过程的监管.水厂净水工艺对农药仅有部分去除效果,相对于4个仅采用常规处理工艺水厂(平均去除率30.0%±13.8%),9个采用臭氧-活性炭深度处理工艺水厂的农药平均去除率较高(54.4%±10.1%).
Distribution of pesticides in typical urban water sources in the lower reaches of the Yangtze River and removal efficiency of treatment plants
This study established a gas chromatography-tandem mass spectrometry(GC-MS/MS)method capable of simultaneously analyzing 190 types of pesticides in water,which was ap-plied to investigate the occurrence of the pesticides in source water and treated water of 13 drinking water treatment plants across five cities located in the lower reaches of the Yangtze River.The in-strument limits of detection ranged from 0.01 to 7.2 ng/L,with a recovery rate between 50.8%and 130.1%.A total of 53 different pesticides were detected in water source,with a total concen-tration level ranging from 198.8 to 759.2 ng/L.The detection frequency of tebuconazole,γ-HCH,metolachlor,hexazinone,and paclobutrazol was 100%,with an average concentration ranging from 11.5 to 63.8 ng/L.Tebuconazole,malathion,carbophenothion,chloroneb,and γ-HCH ex-hibited the highest average concentrations(30.4~101.2 ng/L).The widespread detection of γ-HCH,an organochlorine pesticide that has been banned,suggests the need for enhanced regulation of pesticide production processes.The water treatment plants employing only a conventional treat-ment process(average pesticide removal,30.0%±13.8%)were less effective in pesticide removal compared to the nine plants employing the ozone-activated carbon advanced treatment process(54.4%±10.1%).

The Yangtze RiverSource waterPesticidesDrinking water treatment plantsRe-moval

王荣茂、熊兴安、汤钊、张海峰、杨敏

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中国科学院生态环境研究中心工业废水无害化与资源化国家工程研究中心,北京 100085

中国科学院大学,北京 100049

长江 水源水 农药 饮用水厂 去除

2024

给水排水
亚太建设科技信息研究院,中国建筑设计研究院,中国土木工程学会

给水排水

CSTPCD北大核心
影响因子:0.8
ISSN:1002-8471
年,卷(期):2024.50(8)