首页|南方湖库型原水典型嗅味物质的臭氧/双氧水工艺去除特性研究

南方湖库型原水典型嗅味物质的臭氧/双氧水工艺去除特性研究

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以宁波某地实际原水为进水,对臭氧/双氧水(O3/H2O2)高级氧化技术去除原水中典型嗅味物质—2-甲基异莰醇(2-MIB)的必要性和可行性进行了中试研究.采用对氯苯甲酸作为2-MIB的替代化合物(·OH探针).运行参数包括O3投加量、H2O2/O3投加比、pH和反应时间等.结果表明,相比于仅臭氧投加条件,H2O2的催化作用能明显提高反应速率与去除率.在>50 ng/L的较高浓度2-MIB的进水条件下,为达到出水要求(<10 ng/L),需采用O3/H2O2高级氧化工艺代替仅臭氧氧化,且适宜的H2O2/O3投加比在20%左右.同时,适当提升原水pH也能优化处理效果,在一定程度上减少臭氧投加量.另外,在原水碱度、NOM不高且进水2-MIB浓度较低的情况下,仅通过臭氧氧化也可能实现达标要求.通过运行参数的优化,O3/H2O2工艺可稳定、高效地去除嗅味物质,6 min反应时间即可满足对2-MIB的去除要求.
Study on the peroxone process removal characteristic of typical odors in Southern Lakes and Reservoirs Source Water
In this pilot study,the necessity and feasibility of the prepositive peroxone process for the removal of 2-methylisobornyl(2-MIB),a typical odorous chemicals,was studied using raw water as feed water in a site in Ningbo,China.P-chlorobenzoic acid was used as a replacement compound(·OH probe)for 2-MIB.The operating parameters included O3 dosage,H2O2/O3 dos-age ratio,pH and reaction time.The results showed that the catalytic effect of H2O2 significantly increased the reaction rate and removal rate compared with the ozone-only dosing condition.Under the condition of high concentration of 2-MIB(>50 ng/L),in order to meet the requirement of out-let(<10 ng/L),the peroxone process instead of ozone-only oxidation should be adopted,and the appropriate ratio of H2O2/O3 dosage should be around 20%.At the same time,appropriate in-crease of feed water pH can also optimize the treatment effect,to a certain extent,to reduce the o-zone dosage.In addition,in the case of alkalinity and NOM is not high and the concentration of 2-MIB in the feed water is low,only through the ozone oxidation may also achieve requirements.Through the optimization of the operating parameters,the O3/H2O2 process can remove the odor-ous chemicals stably and efficiently,and the 6 min reaction time can satisfy the removal require-ment of 2-MIB.

Peroxone process2-methylisobornylOdorous chemicalsDrinking water treat-mentOperating parameters

沈万峰、陈琳、郭世柏、魏恒、王昱锜、郭驭、王小(毛)、刘书明

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宁波市水务环境集团有限公司,宁波 315046

清华大学环境学院,北京 100084

臭氧/双氧水高级氧化 2-甲基异莰醇 嗅味 饮用水处理 运行参数

2024

给水排水
亚太建设科技信息研究院,中国建筑设计研究院,中国土木工程学会

给水排水

CSTPCD北大核心
影响因子:0.8
ISSN:1002-8471
年,卷(期):2024.50(11)