材料热处理学报2024,Vol.45Issue(1) :11-21.DOI:10.13289/j.issn.1009-6264.2023-0254

PEMFC金属双极板氮化物涂层的研究进展

Research progress of nitride coatings on PEMFC metal bipolar plate

侯强强 李希超 孙贤伟 赵经香 韦守李 李硕 戴作强 郑莉莉
材料热处理学报2024,Vol.45Issue(1) :11-21.DOI:10.13289/j.issn.1009-6264.2023-0254

PEMFC金属双极板氮化物涂层的研究进展

Research progress of nitride coatings on PEMFC metal bipolar plate

侯强强 1李希超 1孙贤伟 1赵经香 1韦守李 1李硕 1戴作强 1郑莉莉1
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作者信息

  • 1. 青岛大学机电工程学院,山东青岛 266075;青岛大学动力集成及储能系统工程技术中心,山东青岛 266075;电动汽车智能化动力集成技术国家地方联合工程技术中心(青岛),山东青岛 266071
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摘要

质子交换膜燃料电池(PEMFC)金属双极板具有机械强度高、易加工、成本低等优势,但其在PEMFC的酸性环境中容易被腐蚀,从而会对其寿命及导电性产生不利的影响.通过采用氮化物涂层改性的双极板表面结构会变得更加致密,能够提高基体的耐腐蚀性能,从而提高燃料电池的工作寿命.本文从氮化物涂层的种类出发,回顾了近年来氮化物涂层的研究进展.然后介绍了涂层常见的制备方法,同时对其原理进行了分析,对不同的方法制备出的氮化物涂层进行了分析对比.随后总结了不同种类涂层的特点及存在的问题,对不同种类的涂层的耐腐蚀性能进行了比较.最后指出了氮化物涂层存在的问题,并对其未来的发展方向进行了展望.

Abstract

Proton exchange membrane fuel cell(PEMFC)metal bipolar plates have advantages such as high mechanical strength,easy processing and low cost.However,they are prone to corrosion in the acidic environment of PEMFC,which can have adverse effects on their lifespan and electrical conductivity.The surface structure of the bipolar plates modified by nitride coating will become denser,which can improve the corrosion resistance of the substrate and thus improve the working life of fuel cells.This article reviews the research progress of nitride coatings in recent years,starting from the kinds of nitride coatings.Then the common preparation methods for coatings are introduced,and their principles are analyzed.The nitride coatings prepared by different methods are analyzed and compared.Subsequently,the characteristics and existing problems of different kinds of coatings are summarized,and the corrosion resistance performance of different kinds of coatings is compared.Finally,the existing problems of nitride coatings are pointed out,and their future development directions are prospected.

关键词

质子交换膜燃料电池/双极板/氮化物涂层/腐蚀/导电性

Key words

proton exchange membrane fuel cell/bipolar plate/nitride coating/corrosion/electrical conductivity

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基金项目

国家自然科学基金青年基金(52001179)

山东省自然科学基金面上项目(ZR2020ME019)

青岛市关键技术攻关及产业化师范类"面向城际运输的氢燃料动力中型专用车开发及示范"项目(RH2200003807)

出版年

2024
材料热处理学报
中国机械工程学会

材料热处理学报

CSTPCDCSCD北大核心
影响因子:0.958
ISSN:1009-6264
参考文献量9
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