Effect of Mn content on microstructure and properties of as-cast Cu-Ni-Cr alloy
Cu-Ni-Cr-xMn(x=0,1,3,5,7 and 9 mass%)alloys were prepared by atmospheric melting,and the effect of Mn content on microstructure and properties of as-cast Cu-Ni-Cr-xMn alloys was studied by means of optical microscope,scanning electron microscopy,X-ray diffractometer and electronic universal testing machine.The results show that the microstructure of the as-cast Cu-Ni-Cr-xMn alloys is composed of Cu-rich phase(γ1),Ni-rich phase(γ2)and Cr-rich phase,and the addition of Mn significantly changes the segregation form of the second phase in the microstructure of the Cu-Ni-Cr-xMn alloys.The addition of Mn significantly aggregates the Cr element in the Cu-Ni-Cr-xMn alloys microstructure in the Ni-rich zone,and the Cr content in the Ni-rich zone increases significantly.As the Mn content increases,the size of nodular Ni-rich phase(γ2)and Cr-rich phase in the matrix decreases,and their distribution becomes more uniform.The existence of a large number of fine Cr-rich second phase significantly improves the mechanical properties of the alloys.When the Mn content is 3%,the small-sized Cr-rich second phase begins to segregate at the grain boundaries and form a chain like structure,which has a negative effect on the mechanical properties of the alloy.When Mn content is 7%,the effect of Mn atom solid solution strengthening and second phase refinement is significant,and the mechanical properties of the alloy are the best,with a hardness of 195.06 HB and a tensile strength of 401 MPa,respectively.