首页|Mn含量对铸态Cu-Ni-Cr合金组织和性能的影响

Mn含量对铸态Cu-Ni-Cr合金组织和性能的影响

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采用大气熔炼制备了 Cu-Ni-Cr-xMn(x=0、1、3、5、7和9 mass%)合金,采用光学显微镜、扫描电镜、X射线衍射仪和电子万能试验机等研究了 Mn含量对铸态Cu-Ni-Cr-xMn合金显微组织和性能的影响.结果表明:铸态Cu-Ni-Cr-xMn合金的组织由富Cu相(γ1)、富Ni相(γ2)和富Cr相组成,Mn的添加显著改变了 Cu-Ni-Cr-xMn合金组织中第二相的偏聚形式.Mn的加入使Cu-Ni-Cr-xMn合金组织中的Cr元素在富Ni区显著聚集,富Ni区的Cr含量显著增高.随着Mn含量的增加,基体上结节状富Ni相(γ2)和富Cr相尺寸减小,分布更加均匀,大量细小富Cr第二相的存在显著提升了合金的力学性能.当Mn含量为3%时,小尺寸富Cr第二相开始在晶界处偏聚形成链状结构,对合金的力学性能产生了不利影响.当Mn含量为7%时,Mn原子固溶强化及第二相细化效果显著,合金的力学性能最佳,其硬度和抗拉强度分别为195.06 HB和401 MPa.
Effect of Mn content on microstructure and properties of as-cast Cu-Ni-Cr alloy
Cu-Ni-Cr-xMn(x=0,1,3,5,7 and 9 mass%)alloys were prepared by atmospheric melting,and the effect of Mn content on microstructure and properties of as-cast Cu-Ni-Cr-xMn alloys was studied by means of optical microscope,scanning electron microscopy,X-ray diffractometer and electronic universal testing machine.The results show that the microstructure of the as-cast Cu-Ni-Cr-xMn alloys is composed of Cu-rich phase(γ1),Ni-rich phase(γ2)and Cr-rich phase,and the addition of Mn significantly changes the segregation form of the second phase in the microstructure of the Cu-Ni-Cr-xMn alloys.The addition of Mn significantly aggregates the Cr element in the Cu-Ni-Cr-xMn alloys microstructure in the Ni-rich zone,and the Cr content in the Ni-rich zone increases significantly.As the Mn content increases,the size of nodular Ni-rich phase(γ2)and Cr-rich phase in the matrix decreases,and their distribution becomes more uniform.The existence of a large number of fine Cr-rich second phase significantly improves the mechanical properties of the alloys.When the Mn content is 3%,the small-sized Cr-rich second phase begins to segregate at the grain boundaries and form a chain like structure,which has a negative effect on the mechanical properties of the alloy.When Mn content is 7%,the effect of Mn atom solid solution strengthening and second phase refinement is significant,and the mechanical properties of the alloy are the best,with a hardness of 195.06 HB and a tensile strength of 401 MPa,respectively.

Cu-Ni-Cr-xMn alloymicrostructureproperty

朱莹莹、国秀花、李韶林、宋克兴、王强松、孙文明

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河南科技大学材料科学与工程学院,河南洛阳 471023

河南省有色金属材料科学与加工技术重点试验室,河南洛阳 471023

河南省科学院,河南郑州 450052

有研科技集团有限公司有色金属材料制备加工国家重点试验室,北京 100088

有研工程技术研究院有限公司,北京 101407

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Cu-Ni-Cr-xMn合金 显微组织 性能

中国博士后科学基金中国博士后科学基金河南省科技攻关项目河南省博士后科研项目河南省高等学校重点科研项目河南省科技研发计划联合基金

2020T1301722020M68228822210223006420200206321A430014222103810037

2024

材料热处理学报
中国机械工程学会

材料热处理学报

CSTPCD北大核心
影响因子:0.958
ISSN:1009-6264
年,卷(期):2024.45(1)
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