首页|增材制造VNbTiSi轻质难熔共晶高熵合金的组织及力学性能

增材制造VNbTiSi轻质难熔共晶高熵合金的组织及力学性能

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高熵合金与增材制造技术的结合,为极端服役环境下结构复杂部件的一体化制造提供了新的思路.采用激光熔化沉积(LMD)技术成功制备了 VNbTiSi轻质难熔共晶高熵合金,通过显微组织分析筛选出最佳激光功率参数,并对试样进行了室温及高温压缩性能测试.结果表明:VNbTiSi轻质难熔共晶高熵合金表现出了优异的打印性能,最佳工艺参数下制备得到的样品在宏观和微观上均没有出现裂纹.在合金底面及沿构建方向,熔池内部与熔池边界(搭接处)均呈现出不同的形貌,熔池内部由柱状的全共晶组织构成,共晶胞为熔池边界出现较为粗大的(Nb,X)5Si3初生硅化物相.相比铸态组织,激光熔化沉积使得共晶组织的片层间距显著细化.增材制造合金不仅在1000℃下压缩强度可达640 MPa,在1100℃时依然能够保持高于500 MPa的压缩强度,高温压缩性能显著优于铸态VNbTiSi合金.
Microstructure and mechanical properties of VNbTiSi lightweight refractory eutectic high-entropy alloy prepared by additive manufacturing
The combination of high-entropy alloys and additive manufacturing technology provides a new idea for the integrated manufacturing of complex structural components in extreme service environments.VNbTiSi lightweight refractory eutectic high-entropy alloy(REHEA)was successfully prepared by laser melt deposition(LMD)technology.The optimal laser power parameters were selected through microstructure analysis,and the compression properties of the samples were tested at room temperature and high temperature.The results show that the VNbTiSi lightweight refractory eutectic high-entropy alloy has excellent printability,and the samples prepared under the optimal process parameters have no cracks in both macro and micro aspects.At the bottom surface of the alloy and along the build direction,the interior of the molten pool and the boundary(overlap)of the molten pool exhibit different morphology.The interior of the molten pool is composed of columnar fully eutectic structure,and the eutectic cell is a relatively coarse(Nb,X)5Si3 primary silicide phase that appears at the boundary of the melt pool.Compared to the as-cast alloy structure,the laser melting deposition significantly refines the lamellar spacing of the eutectic structure.The compressive strength of the additive manufacturing alloy can not only reach 640 MPa at 1000 ℃,but also maintain a compressive strength higher than 500 MPa at 1100 ℃.The high-temperature compressive property is significantly better than that of as-cast VNbTiSi alloy.

refractory high-entropy alloyadditive manufacturingeutecticlamellar spacinghigh-temperature compression

王俊锋、吴明旭、王舒滨、何毅、杨超、汪东红、疏达、孙宝德

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上海市先进高温材料及其精密成形重点实验室,上海交通大学材料科学与工程学院,上海 200240

中国航发商用航空发动机有限责任公司材料工程部,上海 200241

难熔高熵合金 增材制造 共晶 片层间距 高温压缩

国家重点研发计划国家自然科学基金国家自然科学基金

2022YFB37068005182100152301163

2024

材料热处理学报
中国机械工程学会

材料热处理学报

CSTPCD北大核心
影响因子:0.958
ISSN:1009-6264
年,卷(期):2024.45(3)
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