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激光功率对FeCoCrNiMn高熵合金熔覆层组织与性能的影响

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采用5种激光功率在40CrMnMo钢表面制备了 FeCoCrNiMn高熵合金涂层,采用X射线衍射仪(XRD)、扫描电镜(SEM)、能谱仪(EDS)、维氏显微硬度计、应力分析仪、摩擦磨损试验机和电化学工作站等对涂层的显微组织、物相、力学性能及耐蚀性能进行了研究,分析了激光功率对熔覆层组织与性能的影响.结果表明:激光熔覆制备的FeCoCrNiMn涂层的组织主要为FCC固溶体相,当激光功率大于1400 W时,涂层出现BCC相(α-Fe)结构,组织为树枝晶,晶内为马氏体;随着激光功率的增大,涂层残余应力先减小后增加,在1000 W时达到最小值,为215.3 MPa,涂层的硬度为先增大后减小,1000 W时达最大值215.4HV0.3;激光功率1000 W时涂层的耐磨性最佳,磨损率最低,为1.406×10-5 g·N-1·m-1;激光功率1200 W时涂层的耐腐蚀性最佳,涂层的自腐蚀电位最大,为-0.24 V,自腐蚀电流密度最小,为2.37×10-9 A·cm-2.综合分析试验结果,激光熔覆制备FeCoCrNiMn高熵合金涂层的最佳激光功率为1000 W,此时熔覆涂层的表面成型质量良好、耐磨性能最佳、耐腐蚀性能良好.
Effect of laser power on microstructure and properties of FeCoCrNiMn high entropy alloy cladding coating
FeCoCrNiMn high entropy alloy coatings were prepared on the surface of 40CrMnMo steel by laser cladding with five different laser powers.Microstructure,phase,mechanical properties and corrosion resistance of the coatings were studied by means of X-ray diffraction(XRD),scanning electron microscopy(SEM),energy dispersive spectroscopy(EDS)analysis,Vickers microhardness tester,stress analyzer,friction and wear testing machine and electrochemical workstation.The effect of laser power on the microstructure and properties of the cladding coatings was analyzed.The results show that the microstructure of the FeCoCrNiMn coatings prepared by laser cladding is mainly FCC solid solution phase.When the laser power is greater than 1400 W,the coatings exhibit BCC phase(α-Fe)structure,with dendritic structure and martensite within the crystal.As the laser power increases,the residual stress in the coatings first decreases and then increases,reaching a minimum value of 215.3 MPa at 1000 W,and the hardness of the coatings first increases and then decreases,reaching a maximum value of 215.4 HV0.3 at 1000 W.When the laser power is 1000 W,the wear resistance of the coating is the best and the wear rate is the lowest,which is 1.406×10-5 g·N-1·m-1.When the laser power is 1200 W,the coating has the best corrosion resistance,with the highest self corrosion potential of-0.24 V and the lowest self corrosion current density of 2.37x10-9 A·cm-2.Based on comprehensive analysis of the experimental results,the optimal laser power for preparing FeCoCrNiMn high entropy alloy coatings by laser cladding is 1000 W.At this time,the surface forming quality of the cladding coating is good,with the best wear resistance and good corrosion resistance.

laser claddingFeCoCrNiMn high entropy alloyfrictional propertyelectrochemical performance

刘力豪、徐峰、苏乐、景然、刘文义、冉启科

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陕西理工大学材料科学与工程学院,陕西汉中 723000

西安重装蒲白煤矿机械有限公司,陕西渭南 715500

激光熔覆 FeCoCrNiMn高熵合金 摩擦性能 电化学性能

国家自然科学基金

51701111

2024

材料热处理学报
中国机械工程学会

材料热处理学报

CSTPCD北大核心
影响因子:0.958
ISSN:1009-6264
年,卷(期):2024.45(3)
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