首页|锡含量对富Zr型Ti-Zr-Nb合金显微组织及性能的影响

锡含量对富Zr型Ti-Zr-Nb合金显微组织及性能的影响

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采用非自耗真空电弧炉制备了Ti-49Zr-21Nb-xSn(x=0、0.5、1.0、2.0和4.0 mass%)合金.借助X射线衍射仪(XRD)、扫描电镜(SEM)、万能试验机、电化学工作站及X射线光电子能谱(XPS)等研究了不同含量Sn元素对合金显微组织、力学性能及腐蚀性能的影响.结果表明:随着Sn元素含量的增加,合金的晶粒明显细化,相组成主要为β相,当Sn元素含量超过2%时,在晶界析出(Ti+Zr)5(Nb+Sn)3相.合金的强度随Sn元素含量的增加先升高后降低,当Sn元素含量为1%时,合金的抗拉强度和屈服强度达到最大,分别为1121和1085 Mpa,且伸长率为23.9%.未添加Sn元素时,合金的耐蚀性最佳,添加Sn元素后,合金的耐蚀性逐渐降低,当Sn含量为1%时,合金的自腐蚀电流密度较低,耐蚀性较好.因此,Ti-49Zr-21Nb-1Sn合金具有高的力学性能和较好的腐蚀性能,作为生物医用材料表现出了良好的综合性能.
Effect of Sn content on microstructure and properties of high Zr-containing Ti-Zr-Nb alloy
Ti-49Zr-21Nb-xSn(x=0,0.5,1.0,2.0 and 4.0 mass%)alloys were prepared by non-self-consuming vacuum electric arc furnace.The effect of different contents of Sn elements on microstructure,mechanical properties and corrosion resistance of the alloys was studied using X-ray diffraction(XRD),scanning electron microscopy(SEM),universal testing machine,electrochemical workstation and X-ray photoelectron spectroscopy(XPS).The results show that with the increase of Sn element content,the grain size of the alloys is significantly refined,and the phase composition is mainly composed of β phase.When the Sn element content exceeds 2%,(Ti+Zr)5(Nb+Sn)3 phase precipitates at grain boundaries.The strength of the alloys first increases and then decreases with the increase of Sn element content.When the Sn element content is 1%,the tensile strength and yield strength of the alloy reach their maximum,reaching 1121 and 1085 MPa,respectively,with an elongation of 23.9%.When Sn element is not added,the corrosion resistance of the alloy is the best.After adding Sn element,the corrosion resistance of the alloy gradually decreases.When the Sn content is 1%,the self-corrosion current density of the alloy is relatively lower and the corrosion resistance is better.Therefore,the Ti-49Zr-21Nb-1Sn alloy has high mechanical properties and good corrosion resistance,demonstrating good comprehensive properties as a biomedical material.

Ti-Zr-Nb-Sn alloymicrostructuremechanical propertycorrosion property

程尊鹏、炊鹏飞、李春梅、王晶、郭婉莹、景然、李江华

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陕西理工大学材料科学与工程学院,陕西汉中 723000

陕西理工大学矿渣综合利用环保技术国家地方联合工程实验室,陕西汉中 723000

Ti-Zr-Nb-Sn合金 显微组织 力学性能 腐蚀性能

国家自然科学基金陕西省自然科学基础研究计划项目陕西省教育厅科研计划项目陕西省教育厅科研计划项目

517011112018JQ517019JK018421JK0560

2024

材料热处理学报
中国机械工程学会

材料热处理学报

CSTPCD北大核心
影响因子:0.958
ISSN:1009-6264
年,卷(期):2024.45(3)
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