Effect of Sn content on microstructure and properties of high Zr-containing Ti-Zr-Nb alloy
Ti-49Zr-21Nb-xSn(x=0,0.5,1.0,2.0 and 4.0 mass%)alloys were prepared by non-self-consuming vacuum electric arc furnace.The effect of different contents of Sn elements on microstructure,mechanical properties and corrosion resistance of the alloys was studied using X-ray diffraction(XRD),scanning electron microscopy(SEM),universal testing machine,electrochemical workstation and X-ray photoelectron spectroscopy(XPS).The results show that with the increase of Sn element content,the grain size of the alloys is significantly refined,and the phase composition is mainly composed of β phase.When the Sn element content exceeds 2%,(Ti+Zr)5(Nb+Sn)3 phase precipitates at grain boundaries.The strength of the alloys first increases and then decreases with the increase of Sn element content.When the Sn element content is 1%,the tensile strength and yield strength of the alloy reach their maximum,reaching 1121 and 1085 MPa,respectively,with an elongation of 23.9%.When Sn element is not added,the corrosion resistance of the alloy is the best.After adding Sn element,the corrosion resistance of the alloy gradually decreases.When the Sn content is 1%,the self-corrosion current density of the alloy is relatively lower and the corrosion resistance is better.Therefore,the Ti-49Zr-21Nb-1Sn alloy has high mechanical properties and good corrosion resistance,demonstrating good comprehensive properties as a biomedical material.