首页|长时热暴露对Mar-M247合金组织演变及高温拉伸性能的影响

长时热暴露对Mar-M247合金组织演变及高温拉伸性能的影响

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研究了等轴Mar-M247高温合金在800 ℃热暴露长达24000 h过程中的组织演变规律和800 ℃的高温拉伸强度和塑性.结果表明:热暴露5000 h前,合金的枝晶干二次γ'相、三次γ'相尺寸显著增大,热暴露5000~240000 h时,枝晶干二次γ'相尺寸没有明显变化,枝晶干三次γ'相尺寸略微增长.随热暴露时间延长,枝晶干二次γ'相体积分数增大,三次γ'相体积分数下降.根据两种γ'相的尺寸分布(PSD),两种γ'相的粗化均符合跨界面扩散控制(Trans-interface diffusion-controlled,TIDC)粗化理论;晶界处MC型碳化物通过MC+γ→M23C6+γ'反应逐渐分解,在晶界处形成γ'相膜,包裹着MC型碳化物和M23C6型碳化物.高温拉伸实验结果表明,随热暴露时间的延长,合金的屈服强度和抗拉强度先减小后基本不变,伸长率和断面收缩率先增大后减小再增大,在热暴露5000 h后,屈服强度和抗拉强度分别减小了 164和76 MPa,而在热暴露5000~24000 h时,屈服强度和抗拉强度分别稳定在750和950 MPa.
Effect of long-term thermal exposure on microstructure evolution and high temperature tensile properties of Mar-M247 alloy
Microstructure evolution and 800℃ high temperature tensile strength and plasticity of equiaxed Mar-M247 alloy during thermal exposure at 800℃ for up to 24000 h were investigated.The results show that before 5000 h of thermal exposure,the size of the dendrite secondary and tertiary γ'phases in the alloy increases significantly.However,after 5000-24000 h of thermal exposure,there is no significant change in the size of the dendrite secondary γ'phase,while the size of the dendrite tertiary γ'phase slightly increases.With the increase of thermal exposure time,the volume fraction of the dendrite secondary y'phase increases,while the volume fraction of the dendrite tertiary γ'phase decreases.According to the precipitate size distribution(PSD)of the two γ'phases,the coarsening of both y'phases conforms to the the trans-interface diffusion-controlled(TIDC)coarsening theory.The MC type carbides at the grain boundaries gradually decompose through the MC+γ→M23C6+γ'reaction,forming γ'phase film at the grain boundaries,enveloping the MC type carbides and M23C6 type carbides.The results of high-temperature tensile tests show that with the increase of thermal exposure time,the yield strength and tensile strength of the alloy first decrease and then remain basically unchanged,while the elongation and reduction of area first increase and then decrease and then increase again.After 5000 h of thermal exposure,the yield strength and tensile strength decrease by 164 and 76 MPa,respectively.However,after 5000-24000 h of thermal exposure,the yield strength and tensile strength remain stable at 750 and 950 MPa,respectively.

Ni-based superalloyequiaxed Mar-M247 superalloythermal exposuremicrostructure evolutiontensile property

罗超、商玉洁、高振桓、王西涛、何金珊

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清洁高效透平动力装备全国重点实验室,四川德阳 618000

东方电气集团东方汽轮机有限公司,四川德阳 618336

北京科技大学钢铁共性技术协同创新中心,北京 100083

齐鲁工业大学(山东省科学院),新材料研究所,山东省轻质高强金属材料省级重点实验室,山东济南 250014

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镍基高温合金 等轴Mar-M247合金 热暴露 组织演变 拉伸性能

国家自然科学基金长寿命高温材料国家重点实验室项目山东省高校青年创新科技支撑计划

52201102DEC8300X2023100742020KJA002

2024

材料热处理学报
中国机械工程学会

材料热处理学报

CSTPCD北大核心
影响因子:0.958
ISSN:1009-6264
年,卷(期):2024.45(7)