首页|Co36Ni(37-x)Cr20Al3Ti2Nbx中熵合金的微观组织和力学性能

Co36Ni(37-x)Cr20Al3Ti2Nbx中熵合金的微观组织和力学性能

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采用真空电弧熔炼炉制备了 Co36Ni(37-x)Cr20Al3Ti2Nb,(x=2、3和4,原子分数,%)中熵合金,利用扫描电镜(SEM)、能谱仪(EDS)、透射电镜(TEM)及拉伸试验机等研究了合金的微观组织、力学性能、强化机制及变形机制.结果表明:随着Nb含量的增加,合金晶粒的平均尺寸增大,且晶界处析出相的成分和形状也发生改变.当Nb含量为2%和3%时,析出相为富Al、Nb的片状析出相,当Nb含量提升至4%时,出现了富Ti、Nb的块状析出相.随Nb含量的增加,合金的强度提高,伸长率下降.Nb含量由2%提升到4%,合金的屈服强度由940 MPa提升至1177 MPa,极限抗拉强度由1246 MPa提升至1271 MPa,伸长率由13.67%下降至3.75%.合金强度提升的原因是Nb元素的加入增强了固溶强化和沉淀强化.合金形变初期主要依靠层错诱导形变实现,合金变形后期主要依靠位错运动实现.
Microstructure and mechanical properties of Co36Ni(37-x)Cr20Al3Ti2Nbx medium-entropy alloys
Co36Ni(37-x)Cr20Al3Ti2Nb,(x=2,3 and 4,at%)medium-entropy alloys(MEAs)were prepared by a vacuum arc-melting furnace,and the microstructure,mechanical properties,strengthening mechanism and deformation mechanism of the alloys were studied using scanning electron microscopy(SEM),energy dispersive spectroscopy(EDS)analysis,transmission electron microscopy(TEM)and tensile testing machine.The results show that with the increase of Nb content,the average size of the alloys grains increases,and the composition and shape of precipitates at grain boundaries also change.When the Nb content is 2%and 3%,the precipitates are sheet-like precipitates rich in Al and Nb.When the Nb content increases to 4%,block like precipitates rich in Ti and Nb appear.With the increase of Nb content,the strength of the alloy increases and the elongation decreases.The Nb content increases from 2%to 4%,the yield strength of the alloys increases from 940 MPa to 1177 MPa,the ultimate tensile strength increases from 1246 MPa to 1271 MPa,and the elongation decreases from 13.67%to 3.75%.The reason for the increase in the alloy strength is that the addition of Nb element enhances solid solution strengthening and precipitation strengthening.In the early stage of alloy deformation,it is mainly achieved by the stacking faults-induced deformation,while in the later stage of alloy deformation,it is mainly achieved by dislocation movement.

medium-entropy alloymechanical propertystrengthening mechanismdeformation mechanism

娄照坤、刘继文、林雅婷、王君阳、张璐

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沈阳航空航天大学材料科学与工程学院,辽宁沈阳 110136

沈阳航空航天大学航空制造工艺数字化国防重点学科实验室,辽宁沈阳 110136

中熵合金 力学性能 强化机制 变形机制

沈阳航空航天大学航空制造工艺数字化国防重点学科实验室开放基金资助项目沈阳航空航天大学创新创业训练计划项目

SHSYS202205D202302271902448979

2024

材料热处理学报
中国机械工程学会

材料热处理学报

CSTPCD北大核心
影响因子:0.958
ISSN:1009-6264
年,卷(期):2024.45(7)