首页|Ca元素对Zn-1.5Cu-1.2Mg锌合金组织与性能的影响

Ca元素对Zn-1.5Cu-1.2Mg锌合金组织与性能的影响

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采用金属型铸造法制备了 Zn-1.5Cu-1.2Mg-xCa(x=0、0.1、0.25和0.5,mass%)锌合金,研究了 Ca元素添加量对其微观组织、力学性能和耐腐蚀性能的影响.结果表明:未添加Ca时,合金的初生相为η-Zn,强化相为Mg2Zn11.随着Ca添加量的增加,合金组织中的Mg2Zn11相和Ca的化合物增加,粗大的枝晶细化,并出现了新相.随着Ca添加量的增加,合金的显微硬度增加,而拉伸强度呈先下降后升高的趋势.添加0.5 mass%Ca时,合金的硬度达到最大,为203 HV,未添加Ca时,合金的拉伸强度达到最大,为199 MPa.当Ca添加量达0.1 mass%时,合金的耐腐蚀性能最佳,腐蚀速率为92.1 μm/y.
Effect of Ca element content on microstructure and properties of Zn-1.5Cu-1.2Mg zinc alloy
Zn-1.5Cu-1.2Mg-xCa(x=0,0.1,0.25 and 0.5,mass%)zinc alloys were prepared by metal mold casting method,and the effect of Ca element addition on its microstructure,mechanical properties and corrosion resistance was studied.The results show that when Ca is not added,the primary phase of the alloy is η-Zn,and the strengthening phase is Mg2Zn11.With the increase of Ca addition,the number of Mg2Zn11 phase and Ca compound in the microstructure of the alloys increases,the coarse dendrites are refined,and new phases appear.With the increase of Ca addition,the microhardness of the alloys increases,while the tensile strength shows a trend of first decreasing and then increasing.When 0.5 mass%Ca is added,the hardness of the alloy reaches its maximum value of 203 HV.Without Ca added,the tensile strength of the alloy reaches its maximum value of 199 MPa.When the Ca addition amount reaches 0.1 mass%,the corrosion resistance of the alloy is the best,with a corrosion rate of 92.1 μm/y.

zinc alloymicrostructuremechanical propertycorrosion resistance

张宇轩、王红星、白允强、顾沈逸、王文鑫、徐道翔、史艳慈、周涛、皮峰瑜

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南京工程学院材料科学与工程学院,江苏南京 211167

江苏省先进结构材料与应用技术重点实验室,江苏南京 211167

锌合金 微观组织 力学性能 耐腐蚀性能

江苏省大学生创新创业训练项目江苏高校优秀科技创新团队

202311276153H

2024

材料热处理学报
中国机械工程学会

材料热处理学报

CSTPCD北大核心
影响因子:0.958
ISSN:1009-6264
年,卷(期):2024.45(10)