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高熵合金在电催化氧还原反应中的应用及发展

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开发用于氧气还原反应(ORR)的高效催化剂是提高燃料电池和金属-空气电池性能的关键.然而,ORR是动力学缓慢反应,存在着很高的过电势,从而降低了燃料电池和金属-空气电池的能量转换效率.高熵合金是由5种或5种以上金属元素等(近)物质的量比形成的一种新型合金材料.凭借其独特的组分与结构优势,高熵合金能够高效加速ORR、降低ORR过电势,表现出对ORR的显著催化作用.文章主要综述了高熵合金的结构、性能特点、制备方法以及在催化ORR方面的应用,并提出了挑战和发展展望.
Applications and developments of high-entropy alloys toward electrocatalytic oxygen reduction reaction
The development of highly efficient catalysts for oxygen reduction reaction(ORR)is the key to improve the performance of fuel cells and metal-air batteries.However,ORR is a kinetic slow reaction with high overpotential,which limits the energy conversion efficiency of fuel cells and metal-air batteries.High-entropy alloy is a new kind of alloy,which is consisted of five or more metal ele-ments with(nearly)equimolar ratios.With unique composition and structural advantages,high-entro-py alloy can effectively accelerate ORR kinetics and lower overpotential,showing remarkable catalytic performance toward ORR.In this paper,the structures,properties,preparation methods and applications of high entropy alloys in catalytic ORR were reviewed,and the challenges and development perspec-tives were proposed.

catalystelectrocatalysishigh-entropy alloyoxygen reduction reaction

何小波、丁露、银凤翔、李国儒

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江苏省绿色催化材料与技术重点实验室(常州大学),江苏常州 213164

常州大学石油化工学院,江苏常州 213164

催化剂 电催化 高熵合金 氧还原反应

国家自然科学基金常州市科技计划应用基础研究计划

22078027CJ20220253

2024

常州大学学报(自然科学版)
常州大学

常州大学学报(自然科学版)

影响因子:0.459
ISSN:2095-0411
年,卷(期):2024.36(1)
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