首页|Cu-BTC和石墨烯改性的高性能染料敏化太阳能电池

Cu-BTC和石墨烯改性的高性能染料敏化太阳能电池

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采用Cu-BTC和三维网状石墨烯(3DGNs)对光阳极材料进行改性,通过提高光阳极的比表面积以及提供光生电子的快速输运通道,器件的短路电流和光电转换效率实现了显著的提高.采用SEM和XRD对复合光阳极的微结构进行分析,通过电流-电压曲线和入射光电流转化效率分析其光伏特性.通过调整光阳极中Cu-BTC,3DGNs和TiO2的质量分数实现各种组分的协同作用.优化后,器件的短路电流为(20.5±0.1)mA/cm2,开路电压为(680±2)mV,填充因子为(61.9±0.1)%,能量转换效率为(8.63±0.1)%.
Cu-BTC and graphene co-modified dye sensitize solar cells with high performances
Cu-BTC and three-dimensional graphene networks(3DGNs)were employed to modify the photoanode of dye sensitize solar cells(DSSCs),and the remarkably enhanced short circuit current and incident photon to current conversion efficiency have been achieved.The major reasons are the in-creased BET area of the resulting photoanode and the formed fast transport channel for the photoin-duced electrons.The morphology of photoanode was analyzed by SEM and XRD,and the photocata-lytic performances were detected by current-voltage curves and incident photon to current conversion efficiency and the synergy between the Cu-BTC,3DGNs,and TiO2 can be achieved by adjusting the mass fraction.Moreover,the scattering ability of the photoanode to incident light also can be con-trolled by modulating the size of Cu-BTC.After optimizing the photoanode,the short circuit current,open circuit voltaic,fill factor and energy conversion efficiency of the as-prepared device reached(20.5±0.1)mA/cm2,(680±2)mV,(61.9±0.1)%,(8.63±0.1)%.

Cu-BTCthree-dimensional graphene networksdye sensitize solar cellsphotoanode

唐波、张国良

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常州大学石油与天然气工程学院,江苏常州 213164

Cu-BTC 三维网状石墨烯 染料敏化太阳能电池 光阳极

2024

常州大学学报(自然科学版)
常州大学

常州大学学报(自然科学版)

影响因子:0.459
ISSN:2095-0411
年,卷(期):2024.36(5)