首页|冷喷涂辅助感应重熔合成AlCoxCrFeNiCu高熵合金涂层的显微组织和性能

冷喷涂辅助感应重熔合成AlCoxCrFeNiCu高熵合金涂层的显微组织和性能

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通过冷喷涂辅助感应重熔技术在45钢基体成功制备AlCoxCrFeNiCu(x = 0、0.5、1.0、1.5、2.0,摩尔分数)高熵合金涂层.研究了Co元素含量对冷喷涂辅助合成高熵合金涂层物相、微观组织的影响.结果表明:通过低压冷喷涂辅助感应重熔技术合成的AlCoxCrFeNiCu高熵合金涂层由fcc + bcc双相混合结构组成,涂层组织为等轴树枝晶+晶间组织,其中枝晶为bcc结构,晶间组织为fcc结构.Co含量的变化会引起AlCoxCrFeNiCu高熵合金涂层的晶格畸变状态发生变化,当x = 1.0时,AlCo1CrFeNiCu高熵合金涂层的晶格应变最大.Co元素含量增加会促进AlCoxCrFeNiCu高熵合金涂层中的枝晶数目增加,同时涂层中的树枝晶尺寸也随着Co元素含量增加而增大.涂层中的树枝晶富集Fe、Cr、Co、Ni元素,枝晶间富集Cu元素,Al均匀地分布在整个涂层中.随着Co含量增加,AlCoxCrFeNiCu高熵合金涂层的硬度先增加后减小;当x = 1.0时,AlCo1CrFeNiCu高熵合金涂层的硬度达到562.5 HV,此时涂层的摩擦系数最小,为0.352.
Microstructure and Properties of AlCoxCrFeNiCu High-Entropy Alloy Coating Synthesized by Cold Spraying Assisted Induction Remelting
High-entropy alloy coatings have a very wide range of industrial applications due to their outstanding mechanical properties and good wear resistance.High-entropy alloy coatings of AlCoxCrFeNiCu(x = 0,0.5,1.0,1.5,2.0,mole fraction)on 45 steel substrates were successfully produced by cold spray-ing assisted induction remelting approach.The effect of Co content on the phase and microstructure of cold spraying-assisted high-entropy alloy coating was investigated.The findings reveal that the AlCox-CrFeNiCu high-entropy alloy coating produced using low-pressure cold spraying assisted induction re-melting technique comprises of fcc + bcc two-phase mixed structure,with an equiaxed dendrite + inter-dendritic structure,with the dendrite being bcc and the interdendritic structure being fcc.The lattice distor-tion state of AlCoxCrFeNiCu high-entropy alloy coating changes as the Co element changes;when x = 1.0,the lattice strain of AlCo1CrFeNiCu high-entropy alloy coating is the largest.Increases in Co content promote an increase in dendrite number in AlCoxCrFeNiCu high-entropy alloy coatings,as well as den-drite.The EDS analysis demonstrated that Fe,Cr,Co,and Ni were enriched in the dendrite,Cu was en-riched in the interdendrite,and Al was evenly distributed throughout the coating.With an increase in Co content,the hardness of AlCoxCrFeNiCu high-entropy alloy coating increases first and then decreases.When x = 1.0,the hardness of the AlCo1CrFeNiCu high-entropy alloy coating is 562.5 HV,and the coating minimum's friction coefficient is 0.352.

cold sprayinginduction remeltinghigh-entropy alloy coatingfriction and wear

冯力、王贵平、马凯、杨伟杰、安国升、李文生

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兰州理工大学 材料科学与工程学院 兰州 730050

兰州理工大学 有色金属先进加工与再利用国家重点实验室 兰州 730050

冷喷涂 感应重熔 高熵合金涂层 摩擦磨损

国家自然科学基金国家重点研发计划项目

520752342016YFE0111400

2023

金属学报
中国金属学会

金属学报

CSTPCDCSCD北大核心
影响因子:0.925
ISSN:0412-1961
年,卷(期):2023.59(5)
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