金属学报2023,Vol.59Issue(6) :757-766.DOI:10.11900/0412.1961.2022.00109

Y2O3含量对燃烧合成Fe-Y2O3纳米复合粉末性能的影响

Effects of Y2O3 Content on Properties of Fe-Y2O3 Nanocomposite Powders Synthesized by a Combustion-Based Route

张德印 郝旭 贾宝瑞 吴昊阳 秦明礼 曲选辉
金属学报2023,Vol.59Issue(6) :757-766.DOI:10.11900/0412.1961.2022.00109

Y2O3含量对燃烧合成Fe-Y2O3纳米复合粉末性能的影响

Effects of Y2O3 Content on Properties of Fe-Y2O3 Nanocomposite Powders Synthesized by a Combustion-Based Route

张德印 1郝旭 2贾宝瑞 2吴昊阳 2秦明礼 3曲选辉4
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作者信息

  • 1. 北京科技大学新材料技术研究院 北京 100083;北京科技大学顺德创新学院 佛山 528399
  • 2. 北京科技大学新材料技术研究院 北京 100083
  • 3. 北京科技大学新材料技术研究院 北京 100083;北京科技大学顺德创新学院 佛山 528399;北京科技大学北京材料基因工程高精尖创新中心 北京 100083
  • 4. 北京科技大学新材料技术研究院 北京 100083;北京科技大学北京材料基因工程高精尖创新中心 北京 100083
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摘要

采用溶液燃烧合成技术制备了不同Y2O3含量(质量分数)的Fe-Y2O3纳米复合粉末,分析了 Y2O3含量对制备的复合粉末的微观结构、晶粒尺寸、磁性能和烧结性能的影响.结果表明,制备的Fe-Y2O3纳米复合粉末均呈现由纳米颗粒组成的连通的网状结构,随着Y2O3含量的增加,晶粒尺寸逐渐降低.通过磁性能测试,不含Y2O3的纳米铁粉的饱和磁感应强度为1.97 T,相应的矫顽力为6.4kA/m.随着Y2O3含量的增加,Fe-Y2O3纳米复合粉末的饱和磁感应强度逐渐降低,矫顽力逐渐增大.当Y2O3含量为2%时,Fe-Y2O3纳米复合粉末的饱和磁感应强度为1.45 T,相应的矫顽力为58.9 kA/m.对制备的纳米粉末进行常压烧结,当Y2O3含量低时,该粉末在较低的烧结温度(700℃)下可以获得较高的相对密度,当Y2O3含量增加到1%或2%时,在高的烧结温度(1300 ℃)下也难以实现致密化.

Abstract

Iron-based metal/ceramic nanocomposite materials have attracted increasing attention owing to their outstanding mechanical,electrical,and magnetic properties with potential applications in many industrial fields.However,several technical routes,such as mechanical alloying,sol-gel,and elec-trodeposition,have limitations,including lengthy synthesis processes,complex experimental equipment,and expensive raw materials.In view of the urgent demand for high-quality iron-based metal/ceramic mag-netic nanocomposites,Fe-Y2O3 nanocomposite powders with different Y2O3 contents(mass fraction)have been prepared using a combustion-based route.The effects of the Y2O3 content on the microstructure,grain size,and magnetic and sintering properties of the nanocomposite powders were examined.The Fe-Y2O3 nanocomposite powders exhibited a connected network structure composed of nanoparticles regard-less of the Y2O3 content,but the grain size decreased gradually with increasing Y2O3 content.The magnet-ic performance test showed that the iron nanopowder without Y2O3 had a saturation magnetic induction and coercivity(Hc)of 1.97 T and 6.4 kA/m,respectively.The saturation magnetic induction of the Fe-Y2O3 nanocomposite powders decreased gradually with increasing Y2O3 content,whereas the Hc increased.The saturation magnetic induction and Hc of the Fe-Y2O3 nanocomposite were 1.45 T and 58.9 kA/m,re-spectively,at a Y2O3 content of 2%.The as-synthesized Fe-Y2O3 nanocomposite powders were densified by pressureless sintering.When the Y2O3 content was low,the nanocomposites could reach a higher rela-tive density at a lower sintering temperature of 700℃.In contrast,densification was difficult to achieve when the Y2O3 content was increased to 1%or 2%even at a high sintering temperature of 1300℃.

关键词

溶液燃烧合成/Fe-Y2O3纳米复合粉末/Y2O3含量/微观结构/磁性能

Key words

solution combustion synthesis/Fe-Y2O3 nanocomposite powder/Y2O3 content/micro-structure/magnetic property

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基金项目

北京市自然科学基金(2224104)

广东省基础与应用基础研究基金(2021A1515110202)

出版年

2023
金属学报
中国金属学会

金属学报

CSTPCDCSCD北大核心
影响因子:0.925
ISSN:0412-1961
参考文献量2
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