首页|新型耐热合金SP2215组织与性能的关联性

新型耐热合金SP2215组织与性能的关联性

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针对新型SP2215耐热合金,通过一系列持久及冲击实验,研究了其在不同温度和时间时效处理后组织与性能之间的关联性.结果表明,SP2215合金具有优良的高温组织稳定性,在时效过程中会析出富Cu相、MX相、NbCrN相和M23C6等多种纳米级析出相.在时效早期,随着时效温度升高和时效时间的延长,析出相迅速增多,由于析出相的强化作用,合金的强度迅速增加;同时,合金的冲击韧性显著降低,并发生沿晶断裂,JMA相变动力学模型定量计算表明其主要与M23C6碳化物在晶界的连续析出与长大有关.在时效后期,析出相逐渐保持稳定,无有害相析出,晶粒度始终保持在4.5~5级,优异的高温组织稳定性使得SP2215耐热合金在时效后期具有稳定的力学性能,650和700℃的1 × 105h持久强度分别达到120和70 MPa级别,可实现对HR3C、Super304H等同类耐热合金的国产替代.
Correlation Between Microstructure and Properties of New Heat-Resistant Alloy SP2215
With the improvement of the steam parameters of thermal power units,the requirements put forward for the stress rupture strength and structural stability of heat-resistant materials for boiler su-perheater/reheater pipes become higher.SP2215,as a new heat-resistant alloy,is an excellent candidate for 620-650℃ ultra-supercritical boiler superheater/reheater.In this study,the correlation between micro-structure evolution and properties of the SP2215 heat-resistant alloy aging at different temperatures and time was studied via a series of creep and impact tests.The results show that the SP2215 alloy has ex-cellent microstructure stability in high-temperature condition.Moreover,various nanoscale precipitations such as Cu-rich,MX,NbCrN,and M23C6 phases occur during aging.In the early period of aging,with the increase in aging temperature and aging time,the precipitations increase rapidly,improving the strength of the material;however,the impact toughness of the SP2215 alloy decreases considerably,with substan-tial intergranular fracture caused by the continuous precipitation and growth of M23C6 at the boundary,as shown with the quantitative calculation using the JMA model.In the late period of aging,the precipitations gradually stabilize,and the grain size remains in the range of 4.5-5 grade.As a result,the 1 × 105 h stress rupture strength of the SP2215 alloy at 650 and 700℃ still remain more than 120 and 70 MPa,re-spectively.Hence,the alloy can be used as a domestic replacement for foreign HR3C,Super304H,and other similar heat-resistant alloys.

SP2215 heat-resistant alloylong term agingprecipitationstress rupture strengthproperty

梁凯、姚志浩、谢锡善、姚凯俊、董建新

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北京科技大学材料科学与工程学院 北京 100083

SP2215耐热合金 长期时效 析出相 持久强度 性能

国家自然科学基金国家自然科学基金

5177101752271087

2023

金属学报
中国金属学会

金属学报

CSTPCDCSCD北大核心
影响因子:0.925
ISSN:0412-1961
年,卷(期):2023.59(6)
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