金属学报2023,Vol.59Issue(10) :1346-1354.DOI:10.11900/0412.1961.2021.00497

多相Ni3Al基高温合金微区氧化行为

Oxidation Behavior of Micro-Regions in Multiphase Ni3Al-Based Superalloys

胡敏 周生玉 国京元 胡明昊 李冲 李会军 王祖敏 刘永长
金属学报2023,Vol.59Issue(10) :1346-1354.DOI:10.11900/0412.1961.2021.00497

多相Ni3Al基高温合金微区氧化行为

Oxidation Behavior of Micro-Regions in Multiphase Ni3Al-Based Superalloys

胡敏 1周生玉 1国京元 1胡明昊 1李冲 1李会军 1王祖敏 1刘永长1
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作者信息

  • 1. 天津大学 材料科学与工程学院 水利安全与仿真国家重点实验室 天津 300354
  • 折叠

摘要

以多相Ni3Al基高温合金为对象,通过热处理得到了3种微区结构:枝晶干γ'+ γ两相区、枝晶间β相和包裹着枝晶间β相的γ'包覆层,研究了不同微区组织在1000℃的等温氧化行为.3个微区在氧化初期呈现出不同的氧化行为:γ'包覆层处为明显的双层氧化膜结构,呈现胞状凸起,外部是混合层(NiO、NiFe2O4和Al2O3),内部为单一Al2O3层,而枝晶干γ'+ γ两相区和枝晶间β相形成单层Al2O3膜.随着等温氧化时间的延长,由于晶格扩散占据主导地位,不同微区氧化膜厚度差显著缩小,3个微区的氧化膜组成逐渐趋于一致,形成致密单一的Al2O3层.

Abstract

Ni3Al-based superalloys are widely used in aero-engine parts.In addition to having a good temperature bearing capacity,the oxidation resistance of the alloy is also high.In this work,a multiphase Ni3Al-based superalloy was selected as the experimental material.Three micro-regions(γ'+ γ dendrite,interdendritic β phase,and γ'envelope)containing different phases were obtained by heat treatment.The isothermal oxidation behavior of the micro-regions was studied under 1000℃,where the three micro-regions exhibited different oxidation behaviors at the initial stage of oxidation.The γ'envelope has an obvious double-layer oxide scale showing a cellular bulge.The outer layer is a mixed layer(NiO,NiFe2O4,and Al2O3),and the inner layer is a single Al2O3 layer.However,the γ'+ γ dendrite and the inter-dendritic β phase form a single layer of the Al2O3 film.With increasing isothermal oxidation time,the oxide scale composition of the three micro-regions gradually tends to be the same,forming a dense single Al2O3 layer.

关键词

Ni3Al基高温合金/氧化行为/γ'相/β相

Key words

Ni3Al-based superalloy/oxidation behavior/γ'phase/β phase

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基金项目

国家自然科学基金(51774212)

国家自然科学基金(52122409)

天津市自然科学基金(20JCYBJC00950)

出版年

2023
金属学报
中国金属学会

金属学报

CSTPCDCSCD北大核心
影响因子:0.925
ISSN:0412-1961
参考文献量35
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