首页|W含量对Ti-42Al-5Mn-xW合金相转变行为的影响

W含量对Ti-42Al-5Mn-xW合金相转变行为的影响

扫码查看
以低成本、易变形的Ti-42Al-5Mn合金(原子分数,%)为研究对象,利用DSC、EPMA、EBSD及Pandat热力学计算软件系统研究了W含量(0.5%~1.0%)对合金相变行为和组织的影响.结果表明,随着W含量由0.5%提高至1.0%,合金β单相区开始温度(Tβ)和γ相溶解温度(Tγ-solv)几乎未发生变化,而共析转变温度(Teut)稍有增加.W添加会在一定程度上影响合金固态相变路线,随着W含量增加至0.5%,合金近服役温度下的平衡相由α2 + γ + Laves逐渐演变为βo + α2 + γ + Laves.W添加会对合金片层组织特征产生显著影响.在(γ + α + β)三相区处理时,随着W含量的提高,合金缓冷后组织中片层含量显著降低,当W含量为0.8%和1.0%时,合金组织以γ晶粒和βo相为主,几乎消除了α2/γ层片组织.在(α + β)两相区处理时,合金缓冷后均为近片层组织,且随着W含量由0.5%提高至1.0%,片层组织晶团得到明显细化.
Effect of W Content on the Phase Transformation Behavior in Ti-42Al-5Mn-xW Alloy
Advanced intermetallic β-solidifying γ-TiAl-based alloys have various potential applications in the aerospace and automobile industries due to their low density,functionality at higher temperatures,and high specific strength/modulus.The crucial aspect that needs to be considered when developing a new β-solidifying γ-TiAl alloy is to clarify the influence law of β-stabilizer elements on the phase transfor-mation behavior of γ-TiAl alloys.In this work,the impact of W contents(0.5%-1.0%,atomic fraction)on the phase transformation behavior and microstructure characteristics of Ti-42Al-5Mn-xW(atomic frac-tion)alloy with low cost and superior temperature workability was systematically investigated.The find-ings demonstrate that there were minor changes in the β-phase single region temperature(Tβ)and γphase solvus temperature(Tγ-solv);furthermore,the eutectoid reaction temperature(Teut)increases with the W content from 0.5%to 1.0%.Addition of W influences the solid phase transformation pathway to a cer-tain extent.When the concentration of W increases to 0.5%,the equilibrium phase of the alloy at near service temperature gradually changes from α2 + γ + Laves to βo + α2 + γ + Laves.Additionally,W addition will also have a substantial effect on the lamellar microstructure.The volume fraction of lamellar micro-structure considerably decreased after alloying with(0.5%-1.0%)W for Ti-42Al-5Mn alloy when being treated in the(γ + α + β)triple-phase region followed by furnace cooling.Increasing the W content to 0.8%and 1.0%results in the development of γ and βo grain phases with almost complete removal of α2/γ lamellar structures.However,the W-free and W-bearing Ti-42Al-5Mn alloys show near complete lamellar structures when treated in(α + β)two-phase region followed by furnace cooling.Furthermore,when the content of W increased from 0.5%to 1.0%,an equiaxed grain structure with refined lamellar colonies is typically obtained.

TiAl alloyW contentphase transformationlamellar structuregrain refinement

李小兵、潜坤、舒磊、张孟殊、张金虎、陈波、刘奎

展开 >

季华实验室 材料科学与技术研究部 佛山 528200

中国科学院金属研究所 师昌绪先进材料创新中心 沈阳 110016

TiAl合金 W含量 相变 片层组织 晶粒细化

国家自然科学基金季华实验室科研项目

51971215X210291TL210

2023

金属学报
中国金属学会

金属学报

CSTPCDCSCD北大核心
影响因子:0.925
ISSN:0412-1961
年,卷(期):2023.59(10)
  • 2