首页|高铁转向架用钢G390NH在模拟海洋和工业大气环境下的腐蚀行为及产物演化规律

高铁转向架用钢G390NH在模拟海洋和工业大气环境下的腐蚀行为及产物演化规律

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通过周浸实验结合腐蚀动力学、常规电化学、微观形貌及腐蚀产物成分分析等方法,研究了在模拟加速海洋和工业大气环境下高铁转向架用钢G390NH的腐蚀行为和产物层的演化规律.结果表明,与SO32-相比,Cl-具有更强的穿透能力,生成的锈层以非稳态的Fe3O4和γ-FeOOH为主,该锈层并不能提供非常有效的防护,造成钢的腐蚀速率始终大于6 g/(m2·h).在酸性SO32-环境中,内锈层中富集了耐蚀的Cu,促进了α-FeOOH的生成,增加了锈层在酸性SO32-环境中的抗腐蚀能力.
Corrosion Behavior and Product Evolution of Steel for High-Speed Railway Bogie G390NH in Simulated Marine and Industrial Atmospheric Environment
Atmospheric corrosion is ubiquitous in transportation,infrastructure,and other areas,and it always reduces the service life of materials.Bogie,an important component of the high-speed railway,performs bearing,guiding,damping,traction,and braking.The safe operation of the high-speed railway is inextricably linked to its service performance.However,for the high-speed railway bogie,its service envi-ronment constantly changes as per the operation of the train and being in various atmospheric environ-ments,such as the ocean,pollution,damp-heat,and severe cold for a long time.Therefore,special atten-tion must be paid to the effect of atmospheric corrosion on its service life.The use of weathering steel in bogie has effectively balanced the cost and service life.With the advancement of science and social growth,previous materials are no longer capable of meeting the current service life requirements.G390NH is provided for investigation as a newly designed weathering steel for the bogie.In this study,the corrosion behavior and the product layer evolution law of high-speed rail bogie steel G390NH in simu-lated marine and industrial atmospheric environments are investigated using periodic wetting tests com-bined with corrosion kinetics,conventional electrochemistry,microscopic morphology,and corrosion prod-uct composition analysis.It demonstrates that the two ions(Cl-and SO32-)have different corrosion mecha-nisms on the material.In simulated marine atmosphere environment,Cl-has a higher penetrating capaci-ty,and the rust layer consists of unsteady Fe3O4 and γ-FeOOH;furthermore,coupled with the effect of al-ternating dry and wet,corrosion always maintains a high rate and the rust layer does not give a very ef-fective protection function.However,in the acidic SO32-environment,although the corrosion is accelerat-ed,a layer of corrosion-resistant Cu is enriched in the inner rust layer and simultaneously,and a large amount of α-FeOOH is promoted,which greatly enhances the corrosion resistance of the rust layer.

bogie steelcycle immersion testatmospheric corrosionindustrial atmospheremarine atmospherecorrosion behavior

宋嘉良、江紫雪、易盼、陈俊航、李曌亮、骆鸿、董超芳、肖葵

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北京科技大学 新材料技术研究院 北京 100083

北京科技大学 腐蚀与防护中心 北京 100083

中国电力科学研究院有限公司 北京 100192

转向架用钢 周浸实验 大气腐蚀 工业大气 海洋大气 腐蚀行为

国家重点研发计划项目海洋装备用金属材料及其应用国家重点实验室开放基金表面物理与化学重点实验室学科发展基金

2017YFB0304602SKLMEAK-201908XKFZ201906

2023

金属学报
中国金属学会

金属学报

CSTPCDCSCD北大核心
影响因子:0.925
ISSN:0412-1961
年,卷(期):2023.59(11)
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