精细化工中间体2024,Vol.54Issue(2) :55-58.DOI:10.19342/j.cnki.issn.1009-9212.2024.02.013

柠檬酸/乙二胺碳点的光学性质与导电性能研究

Research on the Optical Properties and Electrical Conductivity of Citric Acid/Ethylenediamine Carbon Dots

赵阿敏 段博文 梁浩楠 刘丹 黎朝晨 葛雯玥 成昭
精细化工中间体2024,Vol.54Issue(2) :55-58.DOI:10.19342/j.cnki.issn.1009-9212.2024.02.013

柠檬酸/乙二胺碳点的光学性质与导电性能研究

Research on the Optical Properties and Electrical Conductivity of Citric Acid/Ethylenediamine Carbon Dots

赵阿敏 1段博文 1梁浩楠 1刘丹 1黎朝晨 1葛雯玥 1成昭1
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作者信息

  • 1. 西安医学院 药学院,陕西 西安 710021
  • 折叠

摘要

为了构筑用于生物学、医学标记的新型光学材料,以柠檬酸为碳源、乙二胺为表面钝化试剂并提供杂原子N,经一步水热反应构筑柠檬酸/乙二胺衍生碳点CA/EDA-2.通过红外光谱测定、共聚焦成像实验及电导率测定,进行CA/EDA-2表面官能团、光学性质与导电性能研究.结果显示,CA/EDA-2材料表面官能团组成包括羟基、氨基及羰基等,荧光性能稳定,HUVEC细胞共聚焦成像显示CA/EDA-2能够定位胞内线粒体,皮尔森系数为0.90.同时,碳点CA/EDA-2导电性能对环境pH敏感,在pH为8.0的弱碱性环境中呈现较好的导电性能,电导率数值为8.43 mS/cm.

Abstract

In order to construct new optical materials for biological and medical labelling,citric acid/ethylenediamine-derived carbon dots CA/EDA-2 were constructed through one-step hydrothermal reaction with citric acid as the carbon source,ethylenediamine as the surface passivation agent and heteroatom N donor.The surface functional groups,optical properties and conductivity of CA/EDA-2 were studied through the measurements of infrared spectrum,confocal imaging and conductivity.It was indicated that CA/EDA-2 were composed of hydroxyl,amino and carbonyl groups,the citric acid/ethylenediamine-derived carbon dots had stable fluorescence performance in the optical analysis and could target mitochondria in HUVEC cells confocal imaging,giving 0.90 as the Pearson's coefficient.Meanwhile,the conductivity of carbon dots CA/EDA-2 was sensitive to the environmental pH,exhibiting better conductivity in a weakly alkaline environment.When the pH value was 8.0,the peak conductivity value was 8.43 mS/cm.

关键词

碳点/荧光性质/共聚焦成像/导电性能

Key words

carbon dots/fluorescent property/confocal imaging/electrical conductivity

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基金项目

西安市科技局项目(22GXFW0122)

国家级大学生创新创业训练计划(202311840013)

西安医学院大学生开放科研实验项目(2023DXS28)

出版年

2024
精细化工中间体
湖南化工研究院

精细化工中间体

CSTPCD
影响因子:0.236
ISSN:1009-9212
参考文献量2
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