精细化工中间体2024,Vol.54Issue(5) :46-51.DOI:10.19342/j.cnki.issn.1009-9212.2024.05.010

碳酸钾活化改性花生壳生物炭对氨氮的吸附性能研究

Adsorption Properties of Ammonia Nitrogen by Activated Peanut Shell Biochar Modified by Potassium Carbonate

李子厚 胡可媛 林榆程 王楚怡 王卫
精细化工中间体2024,Vol.54Issue(5) :46-51.DOI:10.19342/j.cnki.issn.1009-9212.2024.05.010

碳酸钾活化改性花生壳生物炭对氨氮的吸附性能研究

Adsorption Properties of Ammonia Nitrogen by Activated Peanut Shell Biochar Modified by Potassium Carbonate

李子厚 1胡可媛 2林榆程 2王楚怡 2王卫3
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作者信息

  • 1. 中国科学院宁波材料技术与工程研究所先进诊疗材料与技术实验室,浙江宁波 315300;宁波慈溪生物医学工程研究所,浙江宁波 315300
  • 2. 宁波大学科学技术学院,浙江宁波 315300
  • 3. 中国科学院宁波材料技术与工程研究所先进诊疗材料与技术实验室,浙江宁波 315300;宁波大学科学技术学院,浙江宁波 315300
  • 折叠

摘要

以花生壳为原料,碳酸钾为改性剂,在500 ℃氮气中煅烧制成系列生物炭材料(BC、KBC35%、KBC50%和KBC65%).采用XRD、SEM、TEM、BET、FTIR等手段对生物炭的结构进行表征,并研究其对氨氮的吸附性能.结果表明:改性后生物炭呈现明显孔道结构,在pH为7、投加量为2.5 g/L、反应时间80 min时,KBC50%对氨氮吸附效果最佳,去除率达98.26%,吸附量为19.65 mg/g.动力学和等温吸附模型拟合结果表明,KBC50%符合准一阶动力学模型和Langmuir等温吸附模型,表明吸附为单分子层物理吸附为主.

Abstract

Using peanut shells as raw material and potassium carbonate as the modifier,a series of biochar materials(BC,KBC35%,KBC50%and KBC65%)were calcined in nitrogen at 500 ℃.The structures of the carbon materials were characterized by XRD,SEM,TEM,BET and FTIR,and their adsorption properties of ammonia nitrogen were studied.The results showed that the modified biomass carbon exhibited an obvious pore structure.When the pH was 7,the dosage was 2.5 g/L,and the reaction time was 80 min,the adsorption effect of KBC50%on ammonia nitrogen was the best,with a removal rate of 98.26%and an adsorption capacity of 19.65 mg/g.The fitting results of kinetic and isothermal adsorption models showed that KBC50%conforms to the quasi-first-order kinetic model and Langmuir isothermal adsorption model,indicating that the adsorption is mainly monolayer physical adsorption.

关键词

氨氮吸附/生物炭/花生壳/碳酸钾

Key words

ammonia nitrogen adsorption/biochar/peanut shell/potassium carbonate

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基金项目

宁波市自然科学基金项目(2023J173)

国家级大学生创新创业训练项目(202313277012)

出版年

2024
精细化工中间体
湖南化工研究院

精细化工中间体

CSTPCD
影响因子:0.236
ISSN:1009-9212
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