Sulfur powder undergoes a reaction with p-tert-butylphenol in the presence of sodium hydroxide as a base catalyst under a temperature gradient,resulting in the formation of p-tert-butylthiacalix[4]arene.The(1S,2S)-trans-diphenyl-1,2-diaminoethane and(1R,2R)-trans-diphenyl-1,2-diaminoethane undergo cyclization with carbon disulfide,yielding(4S,5S)-trans-diphenylimidazolidine-2-thione and(4R,5R)-trans-diphenylimidazolidine-2-thione,respectively.Then,two novel copper complexes were synthesized via a solvothermal method,followed by solvent evaporation and crystallization,with their single crystal structures characterized through X-ray single crystal diffraction analysis.
关键词
过渡金属配合物/硫杂杯芳烃/单晶
Key words
transition metal complexes/sulfur calixarenes/single crystal
维普
万方数据