首页|微波诱导铜离子负载活性炭去除亚甲基蓝的研究

微波诱导铜离子负载活性炭去除亚甲基蓝的研究

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以微波改性活性炭(PAC)为原料,通过连续6次微波诱导铜离子负载活性炭,制备得到一系列负载金属活性炭,并研究了负载金属活性炭对亚甲基蓝的吸附能力.结果表明,负载金属活性炭对亚甲基蓝的吸附满足二级动力学模型及Langmuir等温吸附模型,属于物理吸附和化学吸附共同作用.相比于PAC,负载金属活性炭1st-Cu@AC对亚甲基蓝的吸附量增加了 12.15%,表明微波诱导铜离子负载活性炭具有一定的改性效果;通过红外光谱、比表面和XRD分析,铜离子负载活性炭与-OH有关,微波使活性炭表面负载氧化铜和氧化亚铜.连续6次微波诱导铜离子负载活性炭6th-Cu@AC的比表面(SBET)高达757.54 m2/g.
Study of Cu2+Loaded Activated Carbon for Removing Methylene Blue by Microwave
Using modified activated carbon(PAC)by microwave(MW)as raw material,series of Cu2+loaded activated carbons were prepared by continuous MW induction,and the adsorption capacity of Cu2+loaded activated carbon for methylene blue(MB)was studied.The results show that the adsorption capacity of Cu2+loaded activated carbon for MB fits the second-order kinetic model and the Langmuir isotherm adsorption model,indicating a combination of physical and chemical adsorption.Compared with PAC,the adsorption capacity of Cu2+loaded activated carbon(1st-Cu@AC)for MB increased by 12.15%,demonstrating the modification effect of MW induction.Through FTIR,BET surface area,and XRD analysis,the Cu2+loaded activated carbon was related to-OH group,and MW makes the surface of the activated carbon supported with copper oxide and cuprous oxide.After six consecutive MW induction,the BET surface area(SBET)of 6th-Cu@AC was still as high as 757.54 m2/g.

loadedmicrowaveactivated carboncopper ionsMB

刘艳萍、高建峰、李子秀、刘江汇、张硕、汪玥戎

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中北大学化学与化工学院,山西太原 030051

中国环境科学研究院清洁生产与循环经济研究中心、国家环境保护生态工业重点实验室,北京 100012

负载 微波 活性炭 铜离子 亚甲基蓝

2024

精细化工中间体
湖南化工研究院

精细化工中间体

CSTPCD
影响因子:0.236
ISSN:1009-9212
年,卷(期):2024.54(6)