江西科学2024,Vol.42Issue(6) :1231-1236.DOI:10.13990/j.issn1001-3679.2024.06.016

增韧材料对PPR管材抗低温冲击性能及结晶行为的影响

The Impact of Toughened Materials on Low-Temperature Impact Resistance and Crystallization Behavior of PPR Pipes

程东红
江西科学2024,Vol.42Issue(6) :1231-1236.DOI:10.13990/j.issn1001-3679.2024.06.016

增韧材料对PPR管材抗低温冲击性能及结晶行为的影响

The Impact of Toughened Materials on Low-Temperature Impact Resistance and Crystallization Behavior of PPR Pipes

程东红1
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作者信息

  • 1. 江西陈氏科技集团股份有限公司,330799,江西,宜春
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摘要

由于PPR管材在寒冷环境下的低温脆性差,提高PPR管材的低温韧性以扩大其应用范围具有重要意义.通过在PPR原料中加入增韧材料制备了具有优异低温韧性的复合PPR管材,研究了增韧材料对PPR管材抗低温冲击性能和结晶行为的影响.结果表明,增韧材料POE、WBG-II、LLDPE能够有效地提高PPR管材在低温环境下的抗冲击性能,PPR/POE和PPR/POE/WBG-II复合管材在-18℃环境下的落锤冲击破损比分别为10%和5%,而PPR/POE/WBG-II/LLDPE复合PPR管材的破损比为35%.结晶行为上POE、WBG-II、LLDPE的加入降低了PPR管材中α晶的结晶度,促进了β晶的形成,从而提高了复合PPR管材的低温韧性.

Abstract

Due to the poor low-temperature brittleness of PPR pipes in cold environments,it is essential to enhance the low-temperature toughness of PPR pipes for their broader applications.Composite PPR pipes with excellent low-temperature toughness were prepared by adding toughened materials to the PPR raw material.This paper studied the effect of toughened materials on the low-temperature impact resistance and crystallization behavior of PPR pipes.The results of low-temperature impact resistance show that the toughened materials(POE,WBG-II,LLDPE)can effectively improve the impact resistance of PPR pipe at low temperatures.The impact breakage ratio of PPR/POE and PPR/POE/WBG-II composite pipe at-18℃is 10%and 5%,respectively,whereas the impact breakage ratio of PPR/POE/WBG-II/LLDPE composite PPR pipe is 35%.In terms of crystallization behavior,the addition of POE,WBG-II,and LLDPE reduces the crystallinity of α crystal in PPR pipe and promotes the formation of β crystal,thus improving the low-temperature toughness of the PPR pipes.

关键词

无规共聚聚丙烯/低温韧性/力学性能

Key words

random copolymer polypropylene/low temperature toughness/mechanical properties

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出版年

2024
江西科学
江西省科学院

江西科学

影响因子:0.286
ISSN:1001-3679
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