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增韧材料对PPR管材抗低温冲击性能及结晶行为的影响

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由于PPR管材在寒冷环境下的低温脆性差,提高PPR管材的低温韧性以扩大其应用范围具有重要意义。通过在PPR原料中加入增韧材料制备了具有优异低温韧性的复合PPR管材,研究了增韧材料对PPR管材抗低温冲击性能和结晶行为的影响。结果表明,增韧材料POE、WBG-II、LLDPE能够有效地提高PPR管材在低温环境下的抗冲击性能,PPR/POE和PPR/POE/WBG-II复合管材在-18℃环境下的落锤冲击破损比分别为10%和5%,而PPR/POE/WBG-II/LLDPE复合PPR管材的破损比为35%。结晶行为上POE、WBG-II、LLDPE的加入降低了PPR管材中α晶的结晶度,促进了β晶的形成,从而提高了复合PPR管材的低温韧性。
The Impact of Toughened Materials on Low-Temperature Impact Resistance and Crystallization Behavior of PPR Pipes
Due to the poor low-temperature brittleness of PPR pipes in cold environments,it is essential to enhance the low-temperature toughness of PPR pipes for their broader applications.Composite PPR pipes with excellent low-temperature toughness were prepared by adding toughened materials to the PPR raw material.This paper studied the effect of toughened materials on the low-temperature impact resistance and crystallization behavior of PPR pipes.The results of low-temperature impact resistance show that the toughened materials(POE,WBG-II,LLDPE)can effectively improve the impact resistance of PPR pipe at low temperatures.The impact breakage ratio of PPR/POE and PPR/POE/WBG-II composite pipe at-18℃is 10%and 5%,respectively,whereas the impact breakage ratio of PPR/POE/WBG-II/LLDPE composite PPR pipe is 35%.In terms of crystallization behavior,the addition of POE,WBG-II,and LLDPE reduces the crystallinity of α crystal in PPR pipe and promotes the formation of β crystal,thus improving the low-temperature toughness of the PPR pipes.

random copolymer polypropylenelow temperature toughnessmechanical properties

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江西陈氏科技集团股份有限公司,330799,江西,宜春

无规共聚聚丙烯 低温韧性 力学性能

2024

江西科学
江西省科学院

江西科学

影响因子:0.286
ISSN:1001-3679
年,卷(期):2024.42(6)