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反应参数对餐厨垃圾超临界水气化行为的影响

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为探究高含水率餐厨垃圾超临界水气化行为,采用间歇式高压石英反应器,分别研究了反应温度(400~550 ℃)、反应时间(1~10min),以及餐厨垃圾质量分数(5%~20%)等条件下对餐厨垃圾超临界水气化行为的影响规律。结果表明,升高反应温度,餐厨垃圾的碳气化率和氢气化率分别提高31。73%和640。77%,气体产物中CO2体积分数减少53。94%,而H2、CH4的体积分数分别增加207。84%、377。62%;增加反应时间,餐厨垃圾的碳气化率和氢气化率在5 min处达到最大,分别升高2。89%和61。49%,气体产物中CO2体积分数降低3。07%,而H2、CH4体积分数分别升高144。27%和148。11%;增大餐厨垃圾占比,餐厨垃圾的碳气化率和氢气化率分别降低76。67%和59。80%,气体产物中CO2、H2、CH4的体积分数分别增加17。24%、217。48%、121。12%。在550℃反应温度、10 min反应时间、5%餐厨垃圾质量分数下,餐厨垃圾的超临界水气化效率最高,可高效实现餐厨垃圾无害化、资源化利用,可为我国实现碳达峰、碳中和目标提供助力。
Effects of Reaction Parameters on the Supercritical Water Gasification Behavior of Food Waste
To clarify the supercritical water gasification behavior of food waste with high moisture content,a batch high-pressure quartz reactor was used to investigate the influence of reaction temperature(400-550℃),reaction time(1~10 min),and mass fractions of food waste(5%-20%)on the supercritical water gasification behavior of food waste.The results showed that as the reaction temperature increased,the carbon and hydrogen gasification rates of food waste significantly increased by 31.73%and 640.77%,respectively.The volume fraction of CO2 in the gas products decreased by 53.94%while the volume fraction of H2 and CH4 gradually increased by 207.84%and 377.62%,respectively.By increasing the reaction time,the carbon and hydrogen gasification rates of food waste reached the maximum value at 5 min and increased by 2.89%and 61.49%,respectively.The volume fraction of CO2 in the gas products decreased by 3.07%,and the volume fractions of H2 and CH4 increased by 144.27%and 148.11%,respectively.With increasing of the mass fractions of food waste,the carbon and hydrogen gasification rates of food waste significantly decreased by 76.67%and 59.80%respectively,while the volume fractions of CO2,H2 and CH4 in the gas products increased by 17.24%,217.48%and 121.12%respectively.At a reaction temperature of 550℃,reaction time of 10 minutes,and a mass fraction of 5%food waste,the supercritical water gasification efficiency of food waste was the highest,which can effectively achieve its harmless and resource utilization,and provides the support for achieving the carbon peak and carbon neutrality goals of China.

food wastesupercritical water gasificationH2reaction temperaturereaction timeproportion

顾凡、阙志刚、付尹宣、黄蓉、程肖帝、蒋海伟、石金明、艾仙斌、邓同辉

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江西省科学院能源研究所,温室气体核算与碳减排江西省重点实验室,南昌 330096

江西省碳中和研究中心,南昌 330096

餐厨垃圾 超临界水气化 氢气 反应温度 反应时间 占比

2024

能源研究与管理
江西省能源研究会 江西省科学院能源研究所 江西省经贸委节能技术中心

能源研究与管理

影响因子:0.207
ISSN:1005-7676
年,卷(期):2024.16(4)