精细石油化工2025,Vol.42Issue(1) :53-56.DOI:10.20075/j.cnki.issn.1003-9384.2025.01.013

石墨炉原子吸收法测定石脑油中痕量砷

DETERMINATION OF TRACE ARSENIC IN NAPHTHA BY GRAPHITE FURNACE ATOMIC ABSORPTION SPECTROMETRY

林清江
精细石油化工2025,Vol.42Issue(1) :53-56.DOI:10.20075/j.cnki.issn.1003-9384.2025.01.013

石墨炉原子吸收法测定石脑油中痕量砷

DETERMINATION OF TRACE ARSENIC IN NAPHTHA BY GRAPHITE FURNACE ATOMIC ABSORPTION SPECTROMETRY

林清江1
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作者信息

  • 1. 中石化(天津)石化公司有限公司,天津 300271
  • 折叠

摘要

从四氢呋喃(THF)有机溶剂稀释试样,以硝酸镍Ni(NO3)2为基体改进剂,采用石墨炉原子吸收法直接进样测定石脑油中的痕量砷,以标准曲线法定量分析.结果表明:石脑油中砷含量在0.5~100.0 μg/kg时的回收率为(100±5)%;砷含量在2~10 μg/kg时,变差系数均小于5%;砷的标准工作曲线呈现良好线性,相关系数为0.999 2.该法能够准确、快速测定石脑油中痕量砷.

Abstract

Trace arsenic in naphtha was directly determined by graphite furnace atomic absorption spectrometry using tetrahydrofuran(THF)as organic solvent to dilute the sample and nickel nitrate Ni(NO3)2 as a matrix modifier.The recovery rate for directly determining arsenic content in naphtha at 0.5-100.0 μg/kg using the standard curve method is(100±5)%,When the arsenic content is be-tween 2-10 μg/kg,the coefficient of variation is less than 5%.The standard working curve of arse-nic shows good linearity with a correlation coefficient of 0.999 2,and can accurately and rapidly deter-mine trace arsenic in naphtha.

关键词

砷元素/石墨炉原子吸收法/原子化温度/标准曲线/基体改进剂

Key words

arsenic element/graphite furnace atomic absorption spectrometry/atomization tempera-ture/standard curve/matrix modifier

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出版年

2025
精细石油化工
中国石化集团资产经营管理有限公司天津石化分公司

精细石油化工

影响因子:0.513
ISSN:1003-9384
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