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石墨炉原子吸收法测定石脑油中痕量砷

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从四氢呋喃(THF)有机溶剂稀释试样,以硝酸镍Ni(NO3)2为基体改进剂,采用石墨炉原子吸收法直接进样测定石脑油中的痕量砷,以标准曲线法定量分析.结果表明:石脑油中砷含量在0.5~100.0 μg/kg时的回收率为(100±5)%;砷含量在2~10 μg/kg时,变差系数均小于5%;砷的标准工作曲线呈现良好线性,相关系数为0.999 2.该法能够准确、快速测定石脑油中痕量砷.
DETERMINATION OF TRACE ARSENIC IN NAPHTHA BY GRAPHITE FURNACE ATOMIC ABSORPTION SPECTROMETRY
Trace arsenic in naphtha was directly determined by graphite furnace atomic absorption spectrometry using tetrahydrofuran(THF)as organic solvent to dilute the sample and nickel nitrate Ni(NO3)2 as a matrix modifier.The recovery rate for directly determining arsenic content in naphtha at 0.5-100.0 μg/kg using the standard curve method is(100±5)%,When the arsenic content is be-tween 2-10 μg/kg,the coefficient of variation is less than 5%.The standard working curve of arse-nic shows good linearity with a correlation coefficient of 0.999 2,and can accurately and rapidly deter-mine trace arsenic in naphtha.

arsenic elementgraphite furnace atomic absorption spectrometryatomization tempera-turestandard curvematrix modifier

林清江

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中石化(天津)石化公司有限公司,天津 300271

砷元素 石墨炉原子吸收法 原子化温度 标准曲线 基体改进剂

2025

精细石油化工
中国石化集团资产经营管理有限公司天津石化分公司

精细石油化工

影响因子:0.513
ISSN:1003-9384
年,卷(期):2025.42(1)