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单级闪蒸-卡琳娜循环发电热力学性能分析与优化

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在卡琳娜循环的基础上,根据梯级用能理论开发单级地热闪蒸-卡琳娜循环技术,分析循环工质的热力学物性,确定系统关键运行参数并建立热力学性能评价指标.基于Peng-Robinson状态方程,借助Aspen HYSYS软件,在氨质量分数为48%、50%和52%时对系统的热效率和㶲效率进行基于遗传算法(Genetic Algorithm)的单目标优化和带精英保留策略的非支配排序遗传算法(Elit-ist Non-dominated Sorting in Genetic Algorithm)的多目标优化.热力学分析结果表明,氨水混合物蒸发压力、液化天然气(LNG)气化压力、天然气输送压力、地热水蒸发压力和氨质量分数对系统热力学性能影响较大;单目标优化结果显示,系统在氨质量分数为52%时获得的最大热效率为34.46%,最大㶲效率为50.65%,较优化前分别提高了12.47%和3.43%;采用LINMAP决策方法从多目标优化结果中搜索获得的系统最优热效率为32.14%、㶲效率为45.31%,对应的氨水混合物蒸发压力、LNG气化压力、天然气输送压力、地热水蒸发压力和氨质量分数分别为1 627.80 kPa、3 232.85 kPa、503.40 kPa、582.55 kPa和52%.
Analysis and optimization of thermodynamic performance of single flash-Kalina cycle in power generation
Based on the Kalina cycle,a single-stage geothermal flash-Kalina cycle was proposed,incorporat-ing the principles of cascade utilization theory.By analyzing the thermodynamic properties of the working fluid in the cycle,the system's crucial operating parameters were determined,and thermodynamic performance eval-uation metrics were established.Utilizing the Peng-Robinson state equation and employing software of Aspen HYSYS,the system's thermal efficiency and exergy efficiency were optimized using single-objective optimiza-tion based on the genetic algorithm(GA)and multi-objective optimization based on NSGA-Ⅱ for ammonia mass fractions of 48%,50%,and 52%.Thermodynamic analysis results revealed that the evaporation pressure of the ammonia-water mixture,LNG gasification pressure,natural gas transmission pressure,geothermal water evap-oration pressure,and ammonia mass fraction had a significant impact on the system's thermodynamic perfor-mance.The single-objective optimization results indicated that the maximum thermal efficiency achieved at an ammonia mass fraction of 52%was 34.46%,with a maximum exergy efficiency of 50.65%,representing im-provements of 12.47%and 3.43%,respectively,compared to the initial optimization.Employing the LINMAP decision method,the system's optimal thermal efficiency was found to be 32.14%,with an exergy efficiency of 45.31%.The corresponding values for the ammonia-water mixture evaporation pressure,LNG gasification pres-sure,natural gas transmission pressure,geothermal water evaporation pressure,and ammonia mass fraction were 1 627.80 kPa,3 232.85 kPa,503.40 kPa,582.55 kPa,and 52%,respectively.

LNG cold energygeothermal energythermodynamic analysisKalina cyclesingle flash

李晚君

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西安石油大学石油工程学院,陕西 西安 710065

LNG冷能 地热能 热力学分析 卡琳娜循环 单级闪蒸

2024

精细石油化工进展
中国石化股份有限公司金陵分公司

精细石油化工进展

影响因子:0.453
ISSN:1009-8348
年,卷(期):2024.25(1)
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