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铋基半导体纳米材料的改性及光催化研究进展

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光催化技术在解决能源危机和环境污染方面受到了广泛的关注,其研究也取得了很多进展.光催化剂在不同领域的作用机制不同,大多数光催化剂都需要克服带隙宽、光生电荷易复合、电荷利用率低等缺陷.由于铋基光催化剂的价带中存在Bi 6s和O 2p杂化轨道,使得大多数Bi基光催化剂具有较窄的可见光利用带隙,因此成为研究热点.本文以铋基半导体为研究对象,针对铋基半导体材料的优缺点,在简单介绍 3种Fe3+掺杂BiOCOOH、氧空位BiOCl/Bi4O5Br2 和CoWO4/Bi2WO6 Z型异质结铋基半导体纳米材料改性研究的基础上,系统综述铋基半导体纳米材料的光催化降解性能及其改性研究进展,以期为相关研究提供参考.
Research progress on modification and photocatalytic degra-dation performance of Bismuth-based semiconductor nanoma-terials
Photocatalysis technology has been widely concerned in solving energy crisis and environmental pollution,and has made a lot of achievements.As the action mechanism of photocatalysts in different fields is different,most photocatalysts need to overcome the defects of wide band gap,easy recombination of photogen-erated charge and low charge utilization rate.Due to the existence of Bi 6s and O 2p hybrid orbitals in valence bands of Bi-based photocatalysts,most Bi-based photocatalysts have relatively narrow visible light utilizable band gaps,so more and more attention has to be paid.Bi-based semiconductors was taken as research object,focusing on the advantages and disadvantages of bismuth-based semiconductor materials.It briefly introduced the modification research of three Bi-based semiconductor nanomaterials designed and synthesized by our re-search group,namely trivalent iron doped BiOCOOH,oxygen vacancy BiOCl/Bi4 O5 Br2,and CoWO4/Bi2 WO6 Z-type heterojunction.The research progress in the modification and photocatalytic degradation performance of Bi-based semiconductor nanomaterials was systematically introduced.

Bi-based semiconductorphotocatalysisheterojunctioncatalystphotodegradation

韩梦阳、陈飘、张晓燕、张胜余、杨水金

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湖北师范大学化学化工学院,湖北 黄石 435002

铋基半导体 光催化 异质结 催化剂 光降解

湖北省大学生创新训练项目

S202310513044

2024

精细石油化工进展
中国石化股份有限公司金陵分公司

精细石油化工进展

影响因子:0.453
ISSN:1009-8348
年,卷(期):2024.25(2)
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