首页|复合型杀菌剂的研究及其在海管中的应用

复合型杀菌剂的研究及其在海管中的应用

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海管内硫酸盐还原菌(SRB)具有较强的抗药性,且H2S含量偏高,给油田生产带来较大的隐患.结合海管工况条件,通过对四羟甲基磷硫酸盐(THPS)、聚六亚甲基胍盐酸盐(PHMG)、羟乙基六氢均三嗪进行复配,采用绝迹稀释法研究复配后杀菌剂对SRB的杀菌性能和抗药性能.结果表明:当THPS∶PHMG∶羟乙基六氢均三嗪质量比为3∶2∶5时,杀菌效果最优;加药质量浓度为100 mg/L,杀菌率达到98%.将复合杀菌剂应用于南海东部油田EP18-1至EP24-2海管,结果表明:现场每周冲击加药为200 mg/L时,SRB由150个/L降低至0.6个/L,H2S由150 mg/L降至20 mg/L左右,可以满足现场生产的技术要求.
Research on a compound fungicide and its application in offshore pipelines
In order to solve the problem that the sulfate-reducing bacteria(SRB)in offshore oil pipelines have strong drug resistance,resulting in high hydrogen sulfide content in the pipelines,combined with the op-erating conditions of the pipelines,tetrahydroxymethyl phosphosulfate(THPS),polyhexamethylene guanidine hydrochloride(PHMG),and hydroxyethyl hexahydromestriazine were compounded,and the bactericidal per-formance and drug resistance of the compounded bactericide to sulfate-reducing bacteria were studied by ex-tinction dilution method.The results showed that when the mass ratio of THPS,PHMG,hydroxyethyl hexahy-drotriazine was 3∶2∶5,the bactericidal effect was optimal,and the bactericidal rate reached 98%at a mass concentration of 100 mg/L.After application in EP18-1 to EP24-2 offshore pipelines in the eastern oil fields of the South China Sea,the results showed that when the on-site weekly impact dosage was 200 mg/L,the SRB decreased from 150 L-1 to 0.6 L-1,and hydrogen sulfide decreased from 150 mg/L to about 20 mg/L,which could meet the technical requirements of on-site production.

compound fungicidesulfate-reducing bacteria(SRB)corrosion of offshore pipelinesTHPSPHMGhydroxyethyl hexahydromestriazine

董辉、郁美莹、冀文雄、马晓飞、陈卓琦、闫冬

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中海油田服务股份有限公司,天津 300450

复合型杀菌剂 硫酸盐还原菌 海管腐蚀 四羟甲基磷硫酸盐 聚六亚甲基胍盐酸盐 羟乙基六氢均三嗪

2024

精细石油化工进展
中国石化股份有限公司金陵分公司

精细石油化工进展

影响因子:0.453
ISSN:1009-8348
年,卷(期):2024.25(3)
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