首页|苯甲羟肟酸-椰油胺组合捕收剂对钨矿浮选行为及机理研究

苯甲羟肟酸-椰油胺组合捕收剂对钨矿浮选行为及机理研究

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通过纯矿物浮选试验、吸附量测试和红外光谱分析,详细探讨了苯甲羟肟酸-椰油胺组合捕收剂对钨矿物的浮选行为及其在钨矿物表面的吸附机理.结果表明:在pH=2.0~12.0,苯甲羟肟酸-椰油胺组合捕收剂对钨矿物的捕收能力明显强于单一使用苯甲羟肟酸;组合捕收剂浮选钨矿物的综合较优pH值为10.0,此时黑钨矿浮选回收率为79.80%,白钨矿浮选回收率为76.68%,远高于单独使用苯甲羟肟酸时黑钨矿浮选回收率37.09%和白钨矿浮选回收率53.96%;经浮选药剂吸附量测试和红外光谱分析可知,苯甲羟肟酸-椰油胺组合捕收剂在黑钨矿和白钨矿表面产生了较强的化学吸附,椰油胺能够增大苯甲羟肟酸在钨矿物表面的吸附量.
The flotation behavior and mechanism of tungsten minerals with benzohydroxamic acid-cocamine combined collectors
Through single mineral flotation experiment,artificial mixed minerals flotation experiment,adsorption capacity and infrared spectrum measurement,the flotation behavior of tungsten minerals and the adsorption mechanism on tungsten minerals surface of benzohydroxamic acid(BHA)and cocamine(ACO)combined collector were studied.The results show that in the range of pH=2.0-12.0,the BHA-ACO combined collector has a stronger collecting ability than BHA on tungsten minerals.The optimum pH value of the combined collector is 10.0,and the recovery rate of wolframite flotation and scheelite flotation is 79.80% and 76.68% ,which are much higher than the recovery rates of wolframite flotation and scheelite flotation of 37.09% and 53.96% when BHA is used alone.ACO could increase the adsorption capacity of BHA on the surface of tungsten minerals,and the BHA-ACO combined collector had significant synergistic effect on wolframite and scheelite surface,resulting in strong chemical adsorption.

benzohydroxamic acidcocaminewolframitescheeliteadsorption mechanism

赖瑞森、邱仙辉、赵冠飞、杨雯慧、邱廷省

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江西理工大学资源与环境工程学院,江西 赣州 341000

江西省矿业工程重点试验室,江西 赣州 341000

苯甲羟肟酸 椰油胺 黑钨矿 白钨矿 吸附作用

国家自然科学基金资助项目江西省教育厅资助项目江西理工大学清江青年英才支持计划资助项目

52164020GJJ190442JXUSTQJYX2020021

2024

有色金属科学与工程
江西理工大学 江西省有色金属学会

有色金属科学与工程

CSTPCD北大核心
影响因子:0.751
ISSN:1674-9669
年,卷(期):2024.15(1)
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