首页|表层氟化环氧树脂的表面电导率和吸水性

表层氟化环氧树脂的表面电导率和吸水性

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为了抑制环氧树脂的表面电荷积累,采用氟/氮混合气对环氧树脂试样进行不同时间(10 min、30 min和60 min)的表面氟化处理,然后对树脂进行全反射红外分析,对电学性能、表面电位衰减特性、吸水性、接触角和湿热老化性能进行测试.结果表明:氟化导致环氧试样表层的化学组成和结构发生了变化,氟化的环氧树脂试样的表面电导率提高了3~4个数量级;随着氟化时间的延长,表面电导率呈先增后降的趋势,并于室温下分别约在419s,986 s和1 296 s内衰减为零;氟化试样的吸水率显著降低,氟化层明显发生了水解.
Surface Conductivity and Water Absorption of Fluorinated Epoxy Resin
In order to inhibit the surface charge accumulation of epoxy resin,we used F2/N2 mixture to treat the surface of epoxy resin samples for 10,30,60 minutes respectively.Then the epoxy resin sampies were characterized by ATR-IR,and their electrical properties,surface potential,water absorption,and contact angel were tested.The results show that the fluorination makes the chemical composition and structure of the surface of epoxy resin samples change,the surface conductivity of the fluorinated epoxy resin samples increases by 3~4 magnitude.With the prolonging of fluorination time,the surface conductivity first increases then decreases,and the surface potential reduce to zero under 419 s,986 s,and 1 296 s respectively at room temperature.The water absorption of the fluorinated samples decreases significantly,and the fluorinated surface is found to be hydrolyzed.

epoxy resinsurface fluorinationsurface conductivityrelative humidity

刘亚强、安振连

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商丘师范学院物理与电气信息学院,河南商丘476000

同济大学电气工程系,上海200092

环氧树脂 表面氟化 表面电导率 相对湿度

国家自然科学基金

51277132

2014

绝缘材料
桂林电器科学研究院

绝缘材料

CSTPCD北大核心
影响因子:0.809
ISSN:1009-9239
年,卷(期):2014.47(6)
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