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氧化铝/聚丙烯复合材料的导热与介电性能仿真优化

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为研究氧化铝(Al2O3)构筑的填料网络对聚丙烯(PP)复合材料导热性能和介电性能的影响规律,本文通过构建Al2O3颗粒随机填充的有限元模型,系统研究了填料填充体积分数、填料粒径以及二元填料的尺寸匹配等因素对Al2O3/PP复合材料热导率和介电常数的影响.结果表明:增加填料的填充体积分数可以显著地桥接Al2O3填料,协同构建互联的导热网络和电位移通路,从而显著提升Al2O3/PP复合材料的热导率和介电常数.对于单一粒径Al2O3/PP复合材料,调控Al2O3 填料尺寸不能有效提高复合材料的热导率和介电常数.引入多尺度填料后,在最佳二元填料(40 μm、10 μm)比例为70∶30下,整体的导热和电位移网络呈现出大尺寸填料的主导骨架和小尺寸填料的桥接分支特征,协同促进Al2O3/PP复合材料达到最优热导率(0.54 W/(m·K))和介电常数(5.6).
Simulation optimization on thermal conductivity and dielectric properties of alumina/polypropylene composites
To investigate the influence of the filler network constructed by alumina(Al2O3)on the thermal and dielectric properties of polypropylene(PP)composites,this study constructed a finite element model of randomly filled Al2O3 fillers,and systematically studied the effects of factors such as filler content,filler particle size,and size matching of binary fillers on the thermal conductivity and dielectric constant of Al2O3/PP composites.The results indicate that increasing the filler content can significantly bridge the Al2O3 filler,synergistically construct an interconnected thermal conductive network and electric displacement pathway,thereby significantly improving the thermal conductivity and dielectric constant of Al2O3/PP composites.For single Al2O3 filled PP composites,the thermal conductivity and dielectric constant of composites cannot be effectively enhanced by regulating the size of Al2O3 filler.After introducing the multiscale fillers,at the optimized binary filler ratio of 70∶30(40 μm∶15 μm),the overall thermal conductivity and electrical displacement networks show the dominant skeleton of large-sized filler and the bridging branch of small-sized fillers features,which synergistically contributes to the Al2O3/PP composite reach the optimal thermal conductivity(0.55 W/(m·K))and dielectric constant(5.6).

aluminapolypropylenethermal conductivitydielectric constantmultiscale optimization

李石琨、李文鹏、史晓宁、赵维佳、王博、张翀、陈新

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中国电力科学研究院有限公司 先进输电技术全国重点实验室,北京 102209

氧化铝 聚丙烯 热导率 介电常数 多尺度优化

2025

绝缘材料
桂林电器科学研究院

绝缘材料

北大核心
影响因子:0.809
ISSN:1009-9239
年,卷(期):2025.58(1)