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电力设备用皱纹纸理化特性分析及模拟改性研究

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绝缘皱纹纸是变压器和互感器及高压电缆等电力设备必须的绝缘材料,目前超(特)高压电力设备用高性能皱纹纸全部依赖进口,为实现高端电力设备用皱纹纸国产化以及提升皱纹纸长期可靠性,亟需开展皱纹纸理化特性及性能提升技术研究.本文开展了不同厂家皱纹纸理化性能测试与对比分析,提炼出影响皱纹纸性能的关键理化参数.通过接枝改性技术向皱纹纸纤维素体系中引入3种官能团,利用Materials Studio软件对改性前后纤维素体系的电、热、力学性能进行分析,探究了不同官能团对纤维素体系各项性能的影响.结果表明:苯环对纤维素体系热性能的提升最为明显,亚甲基长链能提高纤维素体系的绝缘性能,苯环能够提高纤维素体系的力学性能.
Study on physicochemical properties and simulation modification of crepe paper for power equipments
Crepe paper is an essential insulating material for transformers and high-voltage cables.Currently,all high-performance crepe paper is imported.In order to realize the localization of crepe paper for high-end power equipment and improve the long-term reliability of crepe paper,it is urgent to carry out research on the physicochemical properties and performance improvement technology of crepe paper.The physicochemical and macroscopic properties of crepe papers from different manufacturers were tested and analyzed in this paper,and the key physicochemical parameters that affect the performance of crepe papers were extracted.Three functional groups were introduced into the cellulose systems through grafting modification,the properties of the cellulose systems before and after grafting modification were analyzed using Materials Studio software,and the effects of different functional groups on the various properties of the cellulose systems were investigated.The results show that the benzene ring has the most obvious improvement on the thermal properties of the cellulose system,the methylene long chain can improve the insulating properties of the cellulose system,and the benzene ring can improve the mechanical properties of the cellulose system.

crepe paperphysical and chemical propertiesgrafting modificationfunctional groupthermal stability

周海滨、谢志成、潘志城、池明赫、关毅、邓军

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南方电网超高压输电公司电力科研院,广东 广州 510663

哈尔滨理工大学电气与电子工程学院,黑龙江 哈尔滨 150080

哈尔滨理工大学工程电介质及其应用教育部重点实验室,黑龙江 哈尔滨 150080

皱纹纸 理化特性 枝接改性 官能团 热稳定性

2025

绝缘材料
桂林电器科学研究院

绝缘材料

北大核心
影响因子:0.809
ISSN:1009-9239
年,卷(期):2025.58(1)