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煅烧沸石粉对硫氧镁水泥耐水性的影响

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为提高硫氧镁水泥(MOSC)的耐水性,以煅烧沸石粉为掺合料制备MOSC,研究了煅烧前后沸石粉对MOSC凝结时间、力学性能、耐水性、相组成、微观形貌和孔结构的影响.结果表明:掺入煅烧沸石粉提高了MOSC的力学性能,且煅烧前后的沸石粉均可在MOSC体系中反应形成水化硅酸镁(M-S-H)凝胶,降低了MOSC的总孔隙率,提高了MOSC的耐水性,但掺入煅烧沸石粉的MOSC耐水性更优;MOSC中掺入20%经200℃煅烧、升温速率15℃/min处理的沸石粉后,MOSC的耐水性最优,其28 d抗压和抗折强度保留系数分别可达0.91、0.95.
Effect of Calcined Zeolite Powder on Water Resistance of Magnesium Oxysulfate Cement
To improve the water resistance of magnesium oxysulfate cement(MOSC),MOSC were prepared using calcined zeolite powder as an admixture.The effects of calcined zeolite powder before and after calcination on the setting time,mechanical properties,water resistance,phase composition,microstructure,and pore structure of MOSC were investigated.The results indicate that the mechanical properties of MOSC are improved by adding calcined zeolite powder,and the hydrated magnesium silicate gel can be formed by the reaction of zeolite powder before and after calcination in the MOSC system,which reduces the total porosity of MOSC and improves the water resistance of MOSC,but the water resistance of MOSC mixed with calcined zeolite powder is better.After adding 20%zeolite powder that has been calcined at 200℃and treated at a heating rate of 15℃/min,the water resistance of MOSC is optimal.The retention coefficients of compressive and flexural strength at 28 days can reach 0.91 and 0.95,respectively.

magnesium oxysulfate cementcalcinationzeolite powderwater resistancephase compositionmicrostructure

周俊峰、陈啸洋、陈兵、毕万利、关岩

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辽宁科技大学 材料与冶金学院,辽宁 鞍山 114051

辽宁科技大学 化学工程与技术学院,辽宁 鞍山 114051

上海交通大学 船舶海洋与建筑工程学院,上海 200240

辽宁科技大学 科大峰驰镁建材研究院,辽宁 鞍山 114051

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硫氧镁水泥 煅烧 沸石粉 耐水性 相组成 微观形貌

辽宁省教育厅项目国家重点研发计划子课题(十三五)

LJKFZ202201932020YFC1909304

2024

建筑材料学报
同济大学

建筑材料学报

CSTPCD北大核心
影响因子:1.046
ISSN:1007-9629
年,卷(期):2024.27(3)
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