首页|NO2-LDH对减水剂作用效果的影响及机理

NO2-LDH对减水剂作用效果的影响及机理

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采用焙烧还原法制备了亚硝酸根插层水滑石(NO2-LDH),并研究了其对减水剂吸附分散及增强效果的影响.结果表明:NO2-LDH的层间距和结晶度较原碳酸根型镁铝水滑石均略有降低;NO2-LDH与减水剂之间存在阴离子交换,降低了减水剂的吸附分散效果,且减水剂分散效果的降低程度随着NO2-LDH掺量的增加而增大;NO2-LDH对掺减水剂砂浆抗折强度的影响不明显,对抗压强度略有提升;NO2-LDH对萘系高效减水剂分散效果的影响大于对聚羧酸系减水剂的影响.
Influence and Mechanism of NO2-LDH on Effect of Superplasticizer
Nitrite intercalation hydrotalcite(NO2-LDH)was prepared by roasting and reduction method,and its effect on adsorption,dispersion and enhancement of superplasticizer were studied.The results show that the layer spacing and crystallinity of the NO2-LDH are slightly lower than that of protocarbonate type Mg-Al hydrotalcite.There is anion exchange between NO2-LDH and superplasticizer,which reduces the adsorption and dispersion effect of superplasticizer.The decreasing degree of dispersion effect of superplasticizer increases with the increase of NO2-LDH content.NO2-LDH has no obvious effect on the flexural strength of mortar mixed with superplasticizer,but the compressive strength is slightly increased.The effect of NO2-LDH on the dispersion of naphthalene superplasticizer is greater than that of polycarboxylic acid superplasticizer.

nitrite intercalation hydrotalcite(NO2-LDH)superplasticizerdispersion effection exchange

井雪、宋学锋

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西安建筑科技大学 材料科学与工程学院,陕西 西安 710055

亚硝酸根插层水滑石 减水剂 分散效果 离子交换

陕西省科研攻关项目

2018SF-367

2024

建筑材料学报
同济大学

建筑材料学报

CSTPCD北大核心
影响因子:1.046
ISSN:1007-9629
年,卷(期):2024.27(8)
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