首页|一种氮-硫协同高效三聚氰胺苯磺酸盐阻燃剂制备及应用研究

一种氮-硫协同高效三聚氰胺苯磺酸盐阻燃剂制备及应用研究

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本研究合成了一种氮-硫协同高效三聚氰胺苯磺酸盐(MBSA),并运用傅里叶变换红外光谱和热重分析仪对其进行了结构和性能表征.将MBSA添加到聚酰胺6(PA6)中,通过UL-94评级和熔融指数评估了 MBSA/PA6复合材料的阻燃性能和加工性能.结果显示,MBSA表现出优异的热稳定性,其分解温度显著高于PA6的加工温度,适合于高温条件下的加工应用.当MBSA添加量为8%时,MBSA/PA6复合材料达到了 UL-94 V0等级.此外,MBSA的加入显著提高了复合材料的熔融指数,改善了其加工性能,有利于工业生产和成型.本研究揭示了 MBSA作为PA6阻燃添加剂的巨大潜力,为提升聚酰胺类复合材料的性能和应用提供了新的途径和策略.
Study on the synthesis of melamine cyanurate by continuous crystal seed cycling method
In this study,a nitrogen-sulfur synergistic and efficient melamine benzene sulfonate(MBSA)was syn-thesised and its structure and properties were characterised using Fourier transform infrared spectroscopy and ther-mogravimetric analyser.The MBSA was added into polyamide 6(PA6),and the flame retardancy and processabili-ty of MBSA/PA6 composites were evaluated by UL-94 rating and melt index.The results show that MBSA has ex-cellent thermal stability and its decomposition temperature is significantly higher than the processing temperature of PA6,making it suitable for processing applications at high temperatures.The MBSA/PA6 composites achieved UL-94 V0 rating at 8%MBSA addition.In addition,the addition of MBSA significantly increased the melt index of the composites and improved their processability for industrial production and moulding.This study reveals the great potential of MBSA as a flame retardant additive for PA6,which provides new ways and strategies to improve the performance and application of polyamide-based composites.

MelamineBenzenesulfonic acidPolyamideFlame retardant properties

马祥伟、郎俊、钟尧、李鉴、王乙婷、代莉

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四川省精细化工研究设计院有限公司,四川自贡 643000

四川兴晶铧科技有限公司,四川成都 611100

三聚氰胺 苯磺酸 聚酰胺 阻燃性能

2024

聚酯工业
全国聚酯生产技术协作组 大连合成纤维研究设计院股份有限公司

聚酯工业

影响因子:0.2
ISSN:1008-8261
年,卷(期):2024.37(5)