首页|多孔氢键有机框架材料应用于传感和光学材料领域的研究

多孔氢键有机框架材料应用于传感和光学材料领域的研究

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氢键有机框架(HOFs)是一类通过有机连接基团间的氢键自组装形成的聚合物多孔材料.为实现HOF的永久多孔性,需构建稳定且坚固的开放框架,这可以通过精心设计刚性分子结构单元和强相互作用的氢键单元来达成.氢键的柔性和可逆性赋予了 HOF溶液加工性、高结晶度、易于纯化和再生等特性.这些独特的优势使HOF成为研究多孔功能材料的重要平台.近年来,HOF作为多孔功能材料已在气体存储与分离、化学传感、催化、分子识别、生物医学、光学和电学材料等多个关键领域得到广泛应用.
Research on the application of porous hydrogen bonded organic framework materials in the fields of sensing and optical materials
Hydrogen bonded organic frameworks(HOFs)are a type of polymer porous material formed by self-assem-bly of hydrogen bonds between organic linking groups.To achieve permanent porosity of HOF,a stable and robust open framework needs to be constructed,which can be achieved through carefully designed rigid molecular structural units and strongly interacting hydrogen bonding units.The flexibility and reversibility of hydrogen bonds endow HOF solutions with characteristics such as processability,high crystallinity,ease of purification,and regeneration.These unique advantages make HOF an important platform for studying porous functional materials.In recent years,HOF has been widely used as a porous functional material in various key fields such as gas storage and separation,chemi-cal sensing,catalysis,molecular recognition,biomedical,optical,and electrical materials.

Hydrogen bond organic frameworkHOFSensingOptical material

阮春晓、郑庆呈

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福建船政交通职业学院,福建 福州 350007

福建省计量科学研究院,福建 福州 350003

氢键有机框架 HOF 传感 光学材料

2020年福建省中青年教师教育科研项目(科技类)福建船政交通职业学院校科教发展基金

JAT20107120220204

2024

聚酯工业
全国聚酯生产技术协作组 大连合成纤维研究设计院股份有限公司

聚酯工业

影响因子:0.2
ISSN:1008-8261
年,卷(期):2024.37(6)