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稀土金属镥配合物有机电致发光器件性能研究

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稀土元素因其独特的电子结构和丰富的跃迁能级备受关注.利用真空气相沉积法以稀土金属镥配合物Lu(DBM)3Pyphen为发光层,m-MTDATA为空穴注入层,TPD为空穴传输层,制备了结构为ITO/m-MTDATA/TPD/TPD∶Lu(DBM)3Pyphen/Lu(DBM)3Pyphen/LiF/Al的有机电致发光器件.最大亮度和电流效率分别为911 cd/m2和1.1 cd/A,随着电压增加色坐标由(0.485,0.479)移动到(0.391,0.533).器件发光颜色变化具有明显的电压依赖性,为可视信息存储提供了新的思路.
A study on the properties of organic light-emitting devices based on lutetium complex
Rare earth metals have attracted much attention because of their unique electronic structure and abundant transition energy levels.An electroluminescent devices were prepared by vacuum deposition with rare earth metal lutetium complex,Lu(DBM)3Pyphen,as emitting layer.The structure is ITO/m-MTDATA/TPD/TPD∶Lu(DBM)3Pyphen/Lu(DBM)3Pyphen/LiF/Al.m-MTDATA is hole injection layer and TPD is hole transport layer.The maximum brightness and current efficiency are 911 cd/mi2 and 1.1 cd/A,respectively.Significantly during voltage change,emissions of devices shift from 580 nm at 13 V to 550 nm at 26 V.Commission Internationale de L'Eclairage(CIE)coordinates shift from(0.485,0.479)for orange to(0.391,0.533)for yellow green.The color changes of the device with voltage dependence which provides a novel strategy for visual information storage.

Rare earth metalsLutetium complexOrganic light-emitting devices

李建昆、刘力辉、李佳祺、周一江、孙伟博、冯晓东、刘春波

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吉林工程技术师范学院,吉林长春 130052

吉林省绿色合成与新材料研发科技创新中心 吉林长春 130052

吉林师范大学,吉林四平 136000

稀土金属 镥配合物 有机电致发光器件

2025

聚酯工业
全国聚酯生产技术协作组 大连合成纤维研究设计院股份有限公司

聚酯工业

影响因子:0.2
ISSN:1008-8261
年,卷(期):2025.38(1)