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刚果(金)某铜钴矿浸出新工艺

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这是一篇冶金工程领域的文章.刚果(金)某铜钴矿为氧化矿,铜钴含量分别为Cu3.43%和Co 0.42%.本文采用浸出液五级循环浸出工艺浸出铜和钴,在硫酸用量为矿石质量的7.4%、亚硫酸钠用量为理论量的1.68倍、磨矿粒度-74 μm75%、浸出温度45 ℃、浸出液固体积质量比2/1~3/1、单级浸出时间4h的实验条件下,铜浸出率96.85%、钴浸出率95.67%.该工艺在确保铜钴浸出率的情况下,比一级浸出降低硫酸用量6kg/t、浸出过程总溶液量减少约1/4,降低了酸耗、减少了后续钴沉淀和铜萃取处理液量.
A New Process of Leaching Copper and Cobalt from Copper Cobalt Oxide Ore in DR Congo
This is an article in the field of metallurgical engineering.A copper cobalt ore Congo is an oxide ore with Cu 3.43%and Co 0.42%respectively.In this paper,the five stage cycle leaching process of leaching solution was used for the copper and cobalt leaching.The optimum conditions were as follows:the amount of sulfuric acid was 7.4%of the ore mass,the amount of sodium sulfite was 1.68 times of the theoretical amount,the grinding particle size of-74 μm accounts for 75%,leaching temperature was 45 ℃,the single-stage leaching time was 4 hours,and the liquid-solid volume mass ratio was between 2/1 and 3/1,the results showed that the leaching rate of copper and cobalt were 96.85%and 95.67%respectively.According to this leaching process,the amount of sulfuric acid was reduced by 6 kg/t compared with the primary leaching,and the total solution amount in the leaching process was reduced by about 1/4,which made the amount of subsequent cobalt precipitation and copper extraction solution was reduced.

Metallurgical engineeringCopper-cobalt oxide oreCpperCobaltSodium sulfite+sulfiteCountercurrent leaching

曹耀华、王威、刘红召、柳林、张博

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中国地质科学院郑州矿产综合利用研究所,自然资源部多金属矿综合利用评价重点实验室,国家非金属矿资源综合利用工程技术研究中心,河南省黄金资源综合利用重点实验室,河南 郑州 450006

冶金工程 铜钴氧化矿石 硫酸+亚硫酸钠 循环浸出

中国地质调查局地质调查项目

DD20211408

2024

矿产综合利用
中国地质科学院矿产综合利用研究所

矿产综合利用

CSTPCD
影响因子:0.643
ISSN:1000-6532
年,卷(期):2024.45(1)
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