矿产综合利用2024,Vol.45Issue(1) :135-138.DOI:10.3969/j.issn.1000-6532.2024.01.016

刚果(金)某铜钴矿浸出新工艺

A New Process of Leaching Copper and Cobalt from Copper Cobalt Oxide Ore in DR Congo

曹耀华 王威 刘红召 柳林 张博
矿产综合利用2024,Vol.45Issue(1) :135-138.DOI:10.3969/j.issn.1000-6532.2024.01.016

刚果(金)某铜钴矿浸出新工艺

A New Process of Leaching Copper and Cobalt from Copper Cobalt Oxide Ore in DR Congo

曹耀华 1王威 1刘红召 1柳林 1张博1
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作者信息

  • 1. 中国地质科学院郑州矿产综合利用研究所,自然资源部多金属矿综合利用评价重点实验室,国家非金属矿资源综合利用工程技术研究中心,河南省黄金资源综合利用重点实验室,河南 郑州 450006
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摘要

这是一篇冶金工程领域的文章.刚果(金)某铜钴矿为氧化矿,铜钴含量分别为Cu3.43%和Co 0.42%.本文采用浸出液五级循环浸出工艺浸出铜和钴,在硫酸用量为矿石质量的7.4%、亚硫酸钠用量为理论量的1.68倍、磨矿粒度-74 μm75%、浸出温度45 ℃、浸出液固体积质量比2/1~3/1、单级浸出时间4h的实验条件下,铜浸出率96.85%、钴浸出率95.67%.该工艺在确保铜钴浸出率的情况下,比一级浸出降低硫酸用量6kg/t、浸出过程总溶液量减少约1/4,降低了酸耗、减少了后续钴沉淀和铜萃取处理液量.

Abstract

This is an article in the field of metallurgical engineering.A copper cobalt ore Congo is an oxide ore with Cu 3.43%and Co 0.42%respectively.In this paper,the five stage cycle leaching process of leaching solution was used for the copper and cobalt leaching.The optimum conditions were as follows:the amount of sulfuric acid was 7.4%of the ore mass,the amount of sodium sulfite was 1.68 times of the theoretical amount,the grinding particle size of-74 μm accounts for 75%,leaching temperature was 45 ℃,the single-stage leaching time was 4 hours,and the liquid-solid volume mass ratio was between 2/1 and 3/1,the results showed that the leaching rate of copper and cobalt were 96.85%and 95.67%respectively.According to this leaching process,the amount of sulfuric acid was reduced by 6 kg/t compared with the primary leaching,and the total solution amount in the leaching process was reduced by about 1/4,which made the amount of subsequent cobalt precipitation and copper extraction solution was reduced.

关键词

冶金工程/铜钴氧化矿石///硫酸+亚硫酸钠/循环浸出

Key words

Metallurgical engineering/Copper-cobalt oxide ore/Cpper/Cobalt/Sodium sulfite+sulfite/Countercurrent leaching

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基金项目

中国地质调查局地质调查项目(DD20211408)

出版年

2024
矿产综合利用
中国地质科学院矿产综合利用研究所

矿产综合利用

CSTPCD
影响因子:0.643
ISSN:1000-6532
参考文献量9
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