首页|Z-200体系下Pb2+,Zn2+对黄铜矿可浮性的影响及其机理

Z-200体系下Pb2+,Zn2+对黄铜矿可浮性的影响及其机理

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这是一篇矿物加工工程领域的论文.黄铜矿、方铅矿和闪锌矿通常会相互伴(共)生,为了探究Pb2+和Zn2+对黄铜矿浮选行为和表面性质的影响,本研究对黄铜矿进行了单矿物浮选实验,并利用溶液化学计算、Zeta电位和XPS检测等方法,对比研究了 Pb2+和Zn2+对黄铜矿浮选行为和表面性质的影响.黄铜上的Zn2+.矿石可浮性影响的差异.测试结果表明,Pb2+和Zn2+都会吸附在黄铜矿表面,改变黄铜矿表面的Zeta电位,抑制黄铜矿的可浮性,并且随着pH值的升高,抑制作用增强;结合浮选实验结果可知,浮选所处的矿浆pH值范围内,锌主要以Zn(OH)2沉淀的形式吸附在黄铜矿表面从而对黄铜矿的浮选产生抑制效果,所以Zn2+对黄铜矿浮选的抑制效果要比Pb2+显著;且XPS分析结果表明,Pb2+和Zn2+都能在黄铜矿表面形成沉淀物,并以化学吸附的形式出现在黄铜矿表面,从而抑制黄铜矿的可浮性.
Effect of Pb2+,Zn2+ on Floatability of Chalcopyrite in Z-200 System and Its Mechanism
This is an article in the field of mineral processing engineering.Chalcopyrite,galena and sphalerite are usually associated with each other.In order to find out the influence of Pb2+and Zn2+on the flotation behavior and surface characteristics of chalcopyrite,the difference of the influence of Pb2+and Zn2+on the floatability of chalcopyrite was studied by single mineral flotation test,solution chemical calculation,Zeta potential and XPS detection.The results show that Pb2+and Zn2+are adsorbed on the surface of chalcopyrite,which changes the Zeta potential of chalcopyrite surface and inhibits the floatability of chalcopyrite,and the inhibition increases with the increase of pH value.According to the flotation test results,zinc is mainly adsorbed on the surface of chalcopyrite in the form of Zn(OH)2 precipitation in the range of pulp pH,which has an inhibitory effect on the flotation of chalcopyrite.Therefore,the inhibitory effect of Zn2+on the flotation of chalcopyrite is more significant than that of Pb2+and XPS results show that Pb2+and Zn2+can precipitate on the surface of chalcopyrite and exist on the surface of chalcopyrite in the form of chemical adsorption,thus inhibiting the floatability of chalcopyrite.

Mineral processing engineeringChalcopyriteLead zinc ionFloatabilityInhibition

鱼博、何廷树、王鑫、贺寒冰、王宇斌

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西安建筑科技大学 资源工程学院,陕西 西安 710055

铜川润鑫新材料有限公司,陕西 铜川 727018

矿物加工工程 黄铜矿 铅锌离子 可浮性 抑制作用

陕西省科技厅重点研发项目

2018GY-088

2024

矿产综合利用
中国地质科学院矿产综合利用研究所

矿产综合利用

CSTPCD
影响因子:0.643
ISSN:1000-6532
年,卷(期):2024.45(1)
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