矿产综合利用2024,Vol.45Issue(1) :167-173.DOI:10.3969/j.issn.1000-6532.2024.01.022

FeCl3改性活性炭脱硫性能研究

Study on Desulfurization Performance of FeCl3 Modified Activated Carbon

胡谦 刘然 赵俊 吕庆
矿产综合利用2024,Vol.45Issue(1) :167-173.DOI:10.3969/j.issn.1000-6532.2024.01.022

FeCl3改性活性炭脱硫性能研究

Study on Desulfurization Performance of FeCl3 Modified Activated Carbon

胡谦 1刘然 1赵俊 1吕庆1
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作者信息

  • 1. 华北理工大学冶金与能源学院,教育部现代冶金技术重点实验室,河北 唐山 063009
  • 折叠

摘要

这是一篇环境工程领域的论文.实验采用浸渍法,以FeCl3作为改性剂对活性炭进行改性,研究其脱硫能力.实验研究了改性剂浓度、焙烧温度、反应温度对改性活性炭脱硫性能的影响.研究表明,随着改性溶液浓度的增加,活性炭表面附着的Fe2O3随之增加,改性活性炭的比表面积和总孔容均降低,平均孔径增加;随着焙烧温度升高,活性炭表面附着的Fe2O3数量持续增加,焙烧温度超过300 ℃时,活性炭表面的孔隙结构出现烧结现象,降低改性活性炭的脱硫性能;随着反应温度升高,FeCl3/AC-0.15的吸附性能先升高再降低.当FeCl3改性溶液浓度为0.15mol/L,焙烧温度300 ℃,反应温度为60 ℃时,改性活性炭的脱硫效率最高.

Abstract

This is an essay in the field of environmental engineering.The experiment adopts the impregnation method,and uses FeCl3 as the modifier to modify the activated carbon to study its desulfurization ability.The effects of modifier concentration,roasting temperature,and reaction temperature on the desulfurization performance of modified activated carbon were experimentally studied.Studies have shown that as the concentration of the modified solution increases,the Fe2O3 attached to the surface of the activated carbon increases,the specific surface area and total pore volume of the modified activated carbon decrease,and the average pore size increases;as the roasting temperature increases,the amount of Fe2O3 attached to the surface of the activated carbon continues.When the roasting temperature exceeds 300 ℃,the pore structure of the activated carbon surface will be sintered,which will reduce the desulfurization performance of the modified activated carbon;as the reaction temperature increases,the adsorption performance of FeCl3/AC-0.15 first increases and then decreases.When the concentration of FeCl3 modified solutionis 0.15 mol/L,the calcination temperature is 300 ℃,and the reaction temperature is 60 ℃,the desulfurization efficiency of modified activated carbon is the highest.

关键词

环境工程/活性炭/改性/脱硫/浸渍法

Key words

Environmental engineering/Activated carbon/Modified/Desulfurization/Impregnation method

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基金项目

国家自然科学基金项目(51674122)

河北省自然科学基金高端钢铁冶金联合基金项目(E2020209208)

出版年

2024
矿产综合利用
中国地质科学院矿产综合利用研究所

矿产综合利用

CSTPCD
影响因子:0.643
ISSN:1000-6532
参考文献量19
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