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包钢高炉渣中特殊成分对钢渣自粉化行为的影响

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这是一篇冶金工程领域的文章.我国钢渣累计堆存量大,给资源和环境造成巨大压力.本文提出"应用熔融高炉渣与钢渣混合以实现钢渣自粉化"的新思路,就包钢高炉渣中特殊成分(CaF2和CeO2)对钢渣自粉化的影响机理进行系统研究.以分析纯CaO、SiO2、CaF2、CeO2为原料,按n(CaO)∶n(SiO2)=2∶1的配料制备了纯C2S试样,接着分别掺入不同质量分数的CaF2和CeO2,将试样在1 450 ℃恒温焙烧1 h后随炉冷却,探究CaF2和CeO2对C2S自粉化行为的影响规律.结果表明,将CaF2掺入C2S中,当CaF2含量低于2.5%时,对C2S的自粉化几乎没有影响,但在CaF2含量超过2.5%时,试样出现了不同程度的结块现象,影响了 C2S的自粉化,考虑到过量的CaF2会对环境产生影响,因此CaF2的掺入量应控制在2.5%以下;将CeO2掺入C2S中,当CeO2含量为0.25%时,C2S仍能完全自粉化,但CeO2含量超过0.5%时,C2S不再出现自粉化现象,因此CeO2含量必须低于0.25%,C2S自粉化效果较好.
Effect of Special Components in Blast Furnace Slag of Baotou Iron and Steel Company on Self-pulverization Behavior of Steel Slags
This is an article in the field of metallurgical engineering,which proposed a new idea of mixing molten blast furnace slag with steel slag to achieve self-pulverization of steel slag,and systematically studied the influence mechanism of special components of CaF2 and CeO2 in blast furnace slag of Baotou Iron and Steel Company on the self-pulverization of steel slags.Using analytically pure CaO,SiO2,CaF2 and CeO2 as starting materials,pure C2S specimens were prepared with n(CaO)∶n(SiO2)=2∶1,then different mass fractions of CaF2 and CeO2 were added,respectively.The effect of CaF2 and CeO2 on the self-pulverization behavior of C2S was investigated by calcining the specimen at 1 450 ℃ for 1 h and cooling with the furnace.The results showed when CaF2 was incorporated into C2S and the content of CaF2 was less than 2.5%,it had little effect on the self-pulverization of C2S.However,when the content of CaF2 was more than 2.5%,the specimen had different degrees of agglomeration,which affected the self-pulverization of C2S.Considering that excessive CaF2 would affect the environment,the content of CaF2 should be controlled below 2.5%.When CeO2 incorporated into C2S and the content was 0.25%,C2S could still be completely self-pulverized,but when the CeO2 content was more than 0.5%,C2S no longer self-pulverized.Therefore,the CeO2 content must be less than 0.25%,and the self-pulverization effect of C2S was relatively good.

Metallurgical engineeringSteelmaking slagBlast furnace slagSpecial componentsDicalcium silicateSelf-pulverization

陈银胜、罗果萍、郝帅、任杰、安胜利、柴轶凡

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内蒙古科技大学 材料与冶金学院,内蒙古 包头 014010

冶金工程 炼钢渣 高炉渣 特殊成分 硅酸二钙 自粉化

国家重点研发计划项目国家重点研发计划项目

2020YFC19091002020YFC1909105

2024

矿产综合利用
中国地质科学院矿产综合利用研究所

矿产综合利用

CSTPCD
影响因子:0.643
ISSN:1000-6532
年,卷(期):2024.45(4)