矿产综合利用2024,Vol.45Issue(5) :168-175.DOI:10.3969/j.issn.1000-6532.2024.05.024

钛铁矿在混凝土液相环境下的物相转变

Phase Transition of Ilmenite in the Environment of Concrete Pore Solution

白龙 封孝信 刘刚
矿产综合利用2024,Vol.45Issue(5) :168-175.DOI:10.3969/j.issn.1000-6532.2024.05.024

钛铁矿在混凝土液相环境下的物相转变

Phase Transition of Ilmenite in the Environment of Concrete Pore Solution

白龙 1封孝信 1刘刚1
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作者信息

  • 1. 华北理工大学材料科学与工程学院,河北省无机非金属材料实验室,河北省工业固废综合利用技术创新中心,河北 唐山 063210
  • 折叠

摘要

这是一篇陶瓷及复合材料领域的论文.以钛铁矿石为研究对象,分析了FeTiO3 在混凝土液相环境中可能的物相转变,以期为钛铁矿尾矿的利用提供依据.通过热力学计算分析了钛铁矿(FeTiO3)的热力学稳定性;将钛铁矿石粉分别在 20℃和 80℃的模拟混凝土孔溶液中浸泡 28 d和 270 d,采用XRD、SEM/EDS检测矿物转化情况;用钛铁矿石取代部分碎石制备了混凝土,并分别在 20℃和 80℃养护,研究对混凝土强度的影响.热力学计算结果表明,FeTiO3 在有O2 的环境中是不稳定的,可以转化为Fe3O4 或Fe2O3 及TiO2;钛铁矿在模拟混凝土孔溶液中的浸泡实验显示,钛铁矿没有明显变化;混凝土强度实验表明,不论是 20℃还是80℃养护,钛铁矿石取代 5%碎石时,混凝土抗压强度有所提高,取代量为 15%时,抗压强度均又降低,原因为钛铁矿石中的石英发生了碱骨料反应.

Abstract

This is an article in the field of ceramics and composites.Taking ilmenite ore as the research object,the possible phase transformation of FeTiO3 in concrete liquid phase environment was analyzed in order to provide a basis for the utilization of ilmenite tailings.The thermodynamic stability of ilmenite(FeTiO3)was analyzed by thermodynamic calculation.Ilmenite ore powder was soaked in simulated concrete pore solution at 20℃and 80℃for 28 d and 270 d,XRD and SEM/EDS were used to detect mineral transformation.Using ilmenite ore to replace part of the gravel to prepare concrete,the influence on concrete strength at 20℃and 80℃was studied respectively.The results of thermodynamic calculations show that FeTiO3 is unstable in the environment of O2 and converts into Fe3O4 or Fe2O3 and TiO2.The immersion experiment of ilmenite in the simulated concrete pore solution shows that ilmenite has no obvious changes.The concrete strength test shows that at 20℃and 80℃,when ilmenite ore replaces 5%crushed stone,the compressive strength of concrete increases,and when the replacement is 15%,the compressive strength decreases,the reason is that the quartz in the ilmenite ore has undergone an alkali aggregate reaction.

关键词

陶瓷及复合材料/钛铁矿/混凝土孔溶液/物相转变/混凝土/强度

Key words

Ceramics and composites/Ilmenite/Concrete pore solution/Phase transformation/Concrete/Strength

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基金项目

国家自然科学基金(51772098)

出版年

2024
矿产综合利用
中国地质科学院矿产综合利用研究所

矿产综合利用

CSTPCD
影响因子:0.643
ISSN:1000-6532
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