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高炉煤气中NOx的行为特性

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这是一篇冶金工程领域的论文.为降低高炉冶炼过程中NOx的排放,本文以某钢铁厂 2 300 m3 高炉实际生产数据分析为基础,通过热力学计算、数理统计等方法,详细阐述高炉内NOx的生成及还原机理、高炉内部NOx分布特征及影响因素,主要结论如下:高炉煤气中的NOx主要以NO为主,占比约 99%以上,只有极少量NO2;温度是影响风口回旋区前端NOx生成的主要因素,温度由 2 000℃提高至 2 500℃,NO和NO2 的理论生成含量增幅分别达到了 2.56倍和 1.7倍;控制高炉煤气中NOx还原的关键在于控制炉内煤气流的合理分布,应在满足中心、边缘煤气流分配的基本要求下,尽可能使煤气流流经中间环带区域;正常冶炼高炉内还原性气氛可以满足NOx的充分还原,应重点关注亏尺、悬料、休送风等特殊炉况时下游煤气用户NOx的排放水平.
Analysis on the Behavior Characteristics of NOx in Blast Furnace Gas
This is an article in the field of metallurgical engineering.In order to reduce the NOx emission in the blast furnace smelting process,based on the analysis of the actual production data of the 2 300 m3 blast furnace in an iron and steel plant,this paper elaborates on the formation and reduction mechanism of NOx in the blast furnace,and the distribution characteristics and influence of NOx in the blast furnace through thermodynamic calculation,mathematical statistics and other methods.The main conclusions are as follows:NOx in blast furnace gas is mainly NO,accounting for more than 99%,only a very small amount of NO2 and the temperature is the main factor affecting the formation of NOx at the front end of the raceway.When the temperature increases from 2 000℃to 2 500℃,the theoretically generated content of NO and NO2 increases by 2.56 and 1.7 times,respectively,and the key to controlling the reduction of NOx in blast furnace gas is to control the reasonable distribution of gas flow in the furnace.The gas flow should flow through the middle ring zone as much as possible at the basic requirements of gas flow distribution in the center and edge,and the reducing atmosphere in the normal smelting blast furnace can meet the full reduction of NOx,and the NOx emission level of downstream gas users at special furnace conditions such as deficit scale,hanging,blowing-down and reblowing should be paid attention to.

Metallurgical engineeringBlast furnaceNOxReductionBlast kinetic energyGas utilization rate

侯澎、甄常亮、王子兵、徐杰、贺龙、张星、刘欢

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华北理工大学冶金与能源学院,河北 唐山 063200

冶金工程 高炉 NOx 还原 鼓风动能 煤气利用率

2024

矿产综合利用
中国地质科学院矿产综合利用研究所

矿产综合利用

CSTPCD
影响因子:0.643
ISSN:1000-6532
年,卷(期):2024.45(6)